Catalytic oxidation of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid by Co-based MOFs

Bordeiasu, Mihai; Ejsmont, Aleksander; Gościańska, Joanna; Cojocaru, Bogdan; Pârvulescu, Vasile I.; Coman, Simona M.

doi:10.1016/j.apcata.2023.119147

Cited by 9 publications

(3 citation statements)

References 62 publications

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“…A novel core‐shell Co 3 O 4 @CoBTC catalyst that synthesized via replacing the cobalt nitrate precursor with Co 3 O 4 can promote the oxidation of HMF with t‐BuOOH to HMFCA, which reached a 89 % selectivity and 79 % conversion of HMF at 60 °C due to the specific density of the acid and base site as well as the high accessibility of HMF to the active Co sites [146] . Feng et al.…”

Section: Application Of Mofs Derived Catalysts In Platform Chemicals ...mentioning

confidence: 99%

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Zhao,

Du,

Hou

2023

ChemCatChem

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Biomass plays a significant role in replacing fossil resources, and catalytic transformation of platform chemicals to high‐value chemicals is an effective approach to maximize the utilization of biomass. Among of which, efficient and durable catalysts are the heart for upgrading of these platform chemicals, and metal–organic frameworks (MOFs)‐derived catalysts have attracted much attentions due to their suitable and versatile physicochemical properties. In this work, we present a short review on the applications of MOFs‐derived catalysts in upgrading of platform chemicals. The design and synthetic strategies of MOFs‐derived catalysts were summarized in detail, and their application in the catalytic upgrading of glycerol, ethanol, furanic compounds, levulinic acid and vanillin were addressed. The final section outlines the potential industrial applications of MOFs‐derived catalysts for upgrading platform chemicals.

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Section: Application Of Mofs Derived Catalysts In Platform Chemicals ...mentioning

confidence: 99%

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Zhao,

Du,

Hou

2023

ChemCatChem

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“…The reaction could be conducted at low temperatures within a short time. [9] Polyoxometalate was used as an oxidative catalyst to convert HMF to DFF, wherein proton-coupled electron transfer from the synergy between metal oxides promoted the reaction. [10] Cupromoted MnO 2 enhanced the oxidation of HMF to FDCA, wherein the insertion of Cu 2 + into the MnO 2 lattice improved the exchange between Mn 4 + and Mn 3 + during the redox cycle.…”

Section: Introductionmentioning

confidence: 99%

“…A metal‐incorporated MOF catalyst provided the appropriate acid density, basic sites, and good accessibility to improve the catalytic activity and mass transport. The reaction could be conducted at low temperatures within a short time [9] . Polyoxometalate was used as an oxidative catalyst to convert HMF to DFF, wherein proton‐coupled electron transfer from the synergy between metal oxides promoted the reaction [10] .…”

Section: Introductionmentioning

confidence: 99%

Efficient Co‐Cu/MS Catalyst from the Sequential Adsorption and Carbonization of Melamine Foam for the Selective Oxidation of 5‐Hydroxymethylfurfural (HMF)

Le,

Nguyen,

Kongparakul

et al. 2023

ChemistrySelect

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Polyethylenefuranoate, a suitable alternative for polyethylene terephthalate, can be synthesized from biomass‐derived 2,5‐furandicarboxylic acid (FDCA), which is obtained via the selective oxidation of 5‐hydroxymethylfurfural (HMF) over noble or non‐noble metal oxide catalysts. However, the FDCA yields using non‐noble metal catalysts can be improved. Hence, in this study, we developed a series of Co‐ and Cu‐embedded melamine sponge (MS)‐derived carbon catalysts (xCo‐Cu/MS) for HMF oxidation, wherein Co and Cu oxides with different Co : Cu ratios were embedded in carbonized MS. The metals were adsorbed on the MS, followed by carbonization. This strategy allowed the uniform distribution of metal clusters in the carbon texture, which enhanced the catalytic activity for HMF conversion and improved the FDCA yield. The good distribution and small crystal size of Co3O4 significantly increased the active surface area, enhancing the catalytic activity. Compared to Co‐Cu/MS catalysts, the 4Co‐Cu/activated carbon catalyst synthesized via impregnation afforded the maximum FDCA yield (93 %) with 100 % HMF conversion at 170 °C and 7 h. Moreover, oxidative regeneration using H2O2 proved to be the best regeneration method for the MS catalysts, with only a 5 % decrease in the FDCA yield after three cycles.

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Research progress of Co and Mn‐based catalysts for the oxidation of 5‐hydroxymethylfurfural

Tang,

Lv,

Wang

et al. 2024

ChemCatChem

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Biomass is a renewable energy source abundantly available in nature. Their degradation by chemical or biological means produces various transition compounds. These transition compounds can be further transformed into valuable chemicals and biofuels that exhibit a wide range of applications and benefits. Recently, there has been a significant focus on this research area. Among the transition compounds, 5‐hydroxymethylfurfural (HMF), derived from the degradation of hexose, is an important biomass‐based platform compound that has hydroxymethyl and aldehyde functional groups in its molecular structure. This study reviews the recent progress in the transition metal‐catalysed conversion of HMF using Co and Mn to generate high‐value‐added downstream products. Furthermore, the active components, the carbon supporter, the reaction mechanism, the oxidants and the reaction conditions of the catalysts are discussed in detail. The oxidation of HMF deserves further research as an important and complete value‐added process for generating biomass‐based valuable chemicals.

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Catalytic oxidation of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid by Co-based MOFs

Cited by 9 publications

References 62 publications

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Efficient Co‐Cu/MS Catalyst from the Sequential Adsorption and Carbonization of Melamine Foam for the Selective Oxidation of 5‐Hydroxymethylfurfural (HMF)

Research progress of Co and Mn‐based catalysts for the oxidation of 5‐hydroxymethylfurfural

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