Catalyst-free fixation of carbon dioxide into value-added chemicals: a review

Truong, Cong Chien; Mishra, Dinesh Kumar

doi:10.1007/s10311-020-01121-7

Cited by 25 publications

(19 citation statements)

References 206 publications

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“…13 Hydrogen being a high energy material, it can be used as a reagent for CO 2 transformation. 14 The products of CO 2 hydrogenation can be classified into two major categories, such as commodity (e.g., methanol, DMC, etc.) chemicals, and fuels (e.g., hydrocarbons).…”

Section: Introductionmentioning

confidence: 99%

An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

Kanuri

Roy

Chakraborty

et al. 2021

Intl J of Energy Research

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Catalytic hydrogenation of CO 2 to methanol is an exciting avenue to curb the rising CO 2 emissions and generate renewable energy or value-added products.Methanol synthesis via the thermal catalysis route gets increasing emphasis due to its fast kinetics and flexible combination of active components. In the last decade, many studies on CO 2 hydrogenation to methanol have been reported with different kinds of catalysts that have been synthesized and characterized using state-of-the-art surface science tools and techniques. In situ analysis techniques as well as theoretical (eg, density functional theory, Monte Carlo simulations, and Micro-Kinetics modeling) studies have been performed to understand the insights of morphology changes, the interaction of active sites, and the formation of intermediate species under the reaction conditions. In the present review, the advancements on CO 2 to methanol via hydrogenation route have been presented taking into consideration different perspectives spanning across thermodynamic aspects, the influence of reaction temperature, pressure, feed composition, space-velocity, and morphologically tuned novel catalyst on CO 2 conversion and methanol selectivity. Among the reported catalysts, the Al 2 O 3 -supported Cu-Zn catalyst showed better performance with 25% CO 2 conversion and 73% methanol selectivity at 170 C and 50 bar pressure. The CeO 2 -supported Pd-Zn catalyst showed 14% CO 2 conversion and 97% methanol selectivity at 220 C under 20 bar pressure. Also, CeO 2nanorods supported Cu-Ni catalyst showed good performance at 260 C and 30 bars, with around 18% CO 2 conversion and 73% methanol selectivity. Addi-

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Section: Introductionmentioning

confidence: 99%

An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

Kanuri

Roy

Chakraborty

et al. 2021

Intl J of Energy Research

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“…Among various strategies to mitigate the CO 2 problem, CO 2 chemical fixation, namely conversion of CO 2 into value-added chemicals through organic reactions is a very desirable approach. [13][14][15][16] One-pot conversion of olefins (olefin epoxidation and subsequent epoxide-CO 2 cycloaddition) with CO 2 as C 1 building block into valuable cyclic organic carbonates is one of the best choices for CO 2 chemical fixation. [17] MOFs, due to their compositions and functionalities can be easily tunable, they are particularly desirable for such tandem reactions.…”

Section: Introductionmentioning

confidence: 99%

“…As one of the major forms of carbon emissions, CO 2 coming mainly from the burning of fossil fuels brings about a series of environmental problems, including greenhouse effect and ocean acidification. Among various strategies to mitigate the CO 2 problem, CO 2 chemical fixation, namely conversion of CO 2 into value‐added chemicals through organic reactions is a very desirable approach [13–16] . One‐pot conversion of olefins (olefin epoxidation and subsequent epoxide‐CO 2 cycloaddition) with CO 2 as C 1 building block into valuable cyclic organic carbonates is one of the best choices for CO 2 chemical fixation [17] .…”

Section: Introductionmentioning

confidence: 99%

A Novel Cerium(IV)‐Based Metal‐Organic Framework for CO₂ Chemical Fixation and Photocatalytic Overall Water Splitting

Chen

Ren

et al. 2021

ChemSusChem

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Cerium (IV)-based metal-organic frameworks (MOFs) are highly desirable due to their unique potential in fields such as redox catalysis and photocatalysis. However, due to the high reduction potential of Ce IV species in solution, it is still a great challenge to synthesize Ce IV -MOFs with novel structures, which are extremely dominated by the hexanuclear CeÀ O cluster inorganic building units (IBUs). Herein, a CeÀ O IBU chain containing Ce IV -MOF, CSUST-3 (CSUST: Changsha University of Science and Technology), was successfully prepared using the kinetic stabilization study of UiO-66(Ce)-NDC (H 2 NDC = 2,6naphthalenedicarboxylic acid). Furthermore, owing to the superior redox activity, Lewis acidity and semiconductor-like behavior owing to Ce 4 + , activated CSUST-3 was demonstrated to be an excellent catalyst for CO 2 chemical fixation. One-pot synthesis of styrene carbonate from styrene and CO 2 was achieved under mild conditions (1 atm CO 2 , 80 °C, and solvent free). Moreover, activated CSUST-3 was shown to be a remarkable co-catalyst-free photocatalyst for overall water splitting (OWS), rendering 59 μmol g À 1 h À 1 of H 2 and 22 μmol g À 1 h À 1 of O 2 under simulated sunlight irradiation (Na 2 S-Na 2 SO 3 as sacrificial agent).

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“…In fact, it allows converting an important waste (it is well known that carbon dioxide is produced in enormous amounts from the combustion of fossil fuels for the production of energy) into a variety of useful compounds, which can find application as fuels or in the pharmaceutical or material fields. Accordingly, many efforts have been devoted by the scientific community to develop novel efficient and sustainable carboxylation methods, in particular under catalytic conditions, during the last years [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 ].…”

Section: Introductionmentioning

confidence: 99%

Advances in Palladium-Catalyzed Carboxylation Reactions

et al. 2022

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In this short review, we highlight the advancements in the field of palladium-catalyzed carbon dioxide utilization for the synthesis of high value added organic molecules. The review is structured on the basis of the kind of substrate undergoing the Pd-catalyzed carboxylation process. Accordingly, after the introductory section, the main sections of the review will illustrate Pd-catalyzed carboxylation of olefinic substrates, acetylenic substrates, and other substrates (aryl halides and triflates).

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Catalyst-free fixation of carbon dioxide into value-added chemicals: a review

Cited by 25 publications

References 206 publications

An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

A Novel Cerium(IV)‐Based Metal‐Organic Framework for CO₂ Chemical Fixation and Photocatalytic Overall Water Splitting

Advances in Palladium-Catalyzed Carboxylation Reactions

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Catalyst-free fixation of carbon dioxide into value-added chemicals: a review

Cited by 25 publications

References 206 publications

An insight of CO 2 hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

An insight of CO 2 hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

A Novel Cerium(IV)‐Based Metal‐Organic Framework for CO2 Chemical Fixation and Photocatalytic Overall Water Splitting

Advances in Palladium-Catalyzed Carboxylation Reactions

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Product

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An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

An insight of CO ₂ hydrogenation to methanol synthesis: Thermodynamics, catalysts, operating parameters, and reaction mechanism

A Novel Cerium(IV)‐Based Metal‐Organic Framework for CO₂ Chemical Fixation and Photocatalytic Overall Water Splitting