Carborane Polymers and Dendrimers

Grimes, Russell N.

doi:10.1016/b978-0-12-801894-1.00014-7

Cited by 3 publications

(1 citation statement)

References 206 publications

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“…[19][20][21][22] They can be conveniently synthesized from decaborane (B 10 ). [39] Accordingly, the reaction of alkynes with the above boron precursors are usually carried out in an organic solvent such as toluene with typical yields of less than 75 % for the carborane products. It has been reported that the dehydrogenative alkyne-insertion reaction of decaborane in biphasic IL/toluene mixture produces the desired ortho-carborane.…”

Section: Synthesis Of Ortho-carborane In Ionic Liquidsmentioning

confidence: 99%

Ionic Liquids: Recent Advances and Applications in Boron Chemistry

Zhu

Hosmane

2017

Eur J Inorg Chem

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Ionic liquids (ILs) are a type of low‐melting salts, which are generally nonvolatile, have low vapor pressure, very high boiling point, and excellent thermal stability. In addition, they have unique physical and chemical properties including highly variable viscosity, in contrast to common inorganic salts and organic liquids. Consequently, they have found potential applications in the broad area of green chemistry and as electrolytes. Recently, advances have been made in the use of ILs in boron chemistry, and as such various boron‐containing ILs have been reported and their applications in classic organic synthesis have been explored. Interestingly, many boron‐related reactions, such as hydroboration, were explored in ionic liquid media. This microreview mainly focuses on the progress of boron‐containing ILs and reactions involving boron compounds in ILs.

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Section: Synthesis Of Ortho-carborane In Ionic Liquidsmentioning

confidence: 99%

Ionic Liquids: Recent Advances and Applications in Boron Chemistry

Zhu

Hosmane

2017

Eur J Inorg Chem

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Novel Cobalt Bis(dicarbollide) Based on Terminal Alkynes and Their Click‐Reactions

et al. 2020

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Novel cobalt bis(dicarbollide) terminal alkynes with charge‐compensated group were synthesized by the cleavage reactions of oxonium derivatives of cobalt bis(dicarbollide) with N,N‐dimethylprop‐2‐yn‐1‐amine. The solid‐state molecular structures of alkynes prepared from 1,4‐dioxane and tetrahydropyran derivatives of cobalt and iron bis(dicarbollide) were determined by single‐crystal X‐ray diffraction. A series of zwitterionic conjugates of cobalt/iron bis(dicarbollide) with cholesterol were prepared using the copper(I)‐catalyzed azide–alkyne cycloaddition reaction.

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Synthesis of cholesterol derivatives based on closo- and nido-carboranes

Druzina

Stogniy

2021

Russ Chem Bull

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Carborane Polymers and Dendrimers

Cited by 3 publications

References 206 publications

Ionic Liquids: Recent Advances and Applications in Boron Chemistry

Ionic Liquids: Recent Advances and Applications in Boron Chemistry

Novel Cobalt Bis(dicarbollide) Based on Terminal Alkynes and Their Click‐Reactions

Synthesis of cholesterol derivatives based on closo- and nido-carboranes

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