Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ²N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate

Abstract

In the title compound, [Rh(C13H16NO)(C18H15P)(CO)]·0.5C3H6O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl­phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol­ecule, lying about an inversion center, of the acetone solvate. Inter­molecular C—H⋯O hydrogen bonds are observed between a C—H group of the triphenyl­phosphine unit and a carbonyl O atom and between the methyl group of the enamino­ketonato backbone and the solvent O atom. In addition, an intra­molecular inter­action is observed between a C—H group of the triphenyl­phosphine unit and the O atom of the enamino­ketonato ligand.

The crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ 2 O,O′)-(diphenylcyclohexylphosphine-κ P)rhodium(I), C24H25NO3PRh

“…This was confirmed by 1 H, 13 C, and 31 P NMR spectra of the complex. The effective cone angle, θ E [11], of 156.48(2)°is similar to related compounds angles which are in the range of 154-157° [12][13][14][15].…”

Crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ2 O, O′)(triphenylphosphine-κP)rhodium(I), C24H19NO3PRh

“…Furthermore, it was con rmed by 1 H, 13 C, and 31 P NMR spectra of the complex. The e ective cone angle, θ E , [13] of 154.52(3)°that is similar to related compounds angles [14][15][16]. Weak intramolecular hydrogen bond occurs between C14-H14· · · O2 (2.32(1) Å), as well as weak intermolecular hydrogen bond interaction between C4-H4· · · O1 (2.54(1) Å; −x+1, −y+1, −z+1).…”

The crystal structure of carbonyl-[4-(2,4-dichlorophenylamino)pent-3-en-2-onato-κ2 N,O]-(triphenylphosphine-κP)rhodium(I), RhC30H25Cl2NO2P

“…The title complex forms part of a study which investigates complexes containing 2 ]-type complex will be substituted by triphenyl phosphine, with the product being one of two possible isomers [5], has been confirmed [6][7][8]. In each case the CO-group trans to the N-atom will be substituted, attributed to the larger trans-influence of the N-donor atom over the O-atom.…”