Crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ² O, O′)(triphenylphosphine-κP)rhodium(I), C₂₄H₁₉NO₃PRh

Abstract

C 24 H 19 NO 3 PRh, triclinic, P¯ (no. 2), a = 9.1734(16) Å, b = 9.5433(18) Å, c = 12.342(2) Å, α = 92.400(6)°, β = 105.460 (5) CCDC no.: 1463131The gure shows the asymmetric unit of the title structure. Tables 1-3 contain details of the methods used and a list of the atoms including atomic coordinates and displacement parameters.

The crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ 2 O,O′)-(diphenylcyclohexylphosphine-κ P)rhodium(I), C24H25NO3PRh

“…This was confirmed by 1 H, 13 C, and 31 P NMR spectra of the complex. The effective cone angle, θ E [11], of 156.48(2)°is similar to related compounds angles which are in the range of 154-157° [12][13][14][15].…”

(N-Benzoyl-N-phenylhydroxylaminato)carbonyl(triphenylarsine)rhodium(I)

“…The coordination environment in the molecule of [Rh(BPHA)-(AsPh 3 )(CO)] is distorted square planar, as shown by the small O1-Rh-O2 bite angle of 79.53 (7) , which is similar to the bite angles of related structures with O,O-binding five-membered chelate rings reported in the literature (Elmakki et al, 2017). The C02-Rh-O2 and C02-Rh-O1 angles involving the C02 O02 carbonyl ligand were also found to deviate from ideal values, at 99.31 (9) and 178.39 (10) , respectively, similar to those of related structures (Elmakki et al, 2016).…”

Crystal structure of carbonyl(2-methylquinolin-8-olato-κ2 N,O)(triphenylarsine-κAs)rhodium(I), C29H23AsNO2Rh

“…altering the electronic and steric properties of the ligand resulting in significant changes in the outcome of the catalytic process. These complexes have been studied intensively for potential application in catalytic hydroformylation, hydrogenation, carbonylation, and decarbonylation [8][9][10][11][12][13][14][15][16][17][18][19]. The coordination mode in the title complex is similar to the complexes reported previously [20].…”