Abstract:Reinforced concrete (RC) has been commonly used as a construction material for decades due to its high compressive strength and moderate tensile strength. However, these two properties of RC are frequently hampered by degradation. The main degradation processes in RC structures are carbonation and the corrosion of rebars. The scientific community is divided regarding the process by which carbonation causes structural damage. Some researchers suggest that carbonation weakens a structure and makes it prone to re… Show more
“…In general, mortars with a higher sand content (1:2) showed reduced resistance to carbonation and water absorption, which was consistent with the previous research by Huang et al [ 157 ], which showed that CO 2 gas penetrates the concrete surface through the sand-cement gap [ 157 ]. This means that increasing the volume of sand in concrete also increases CO 2 penetration [ 158 ]. Duan et al [ 156 ] noted an improvement in carbonation resistance by 77%, 62%, and 42% for fluidized bed fly ash geopolymer paste samples containing 1%, 3%, and 5% NT, respectively, after 180 days of exposure.…”
Section: Results Of Mechanical Properties Of Modified Cement Mortarsmentioning
This article presents a short overview of modified cements with photocatalytic activity. First, the types and three main methods of obtaining photoactive cements are presented. The most frequently used modification method is the incorporation of a photocatalyst into the total mass of the cement. The second group analyzed is cements obtained by applying a thin layer of photoactive materials, e.g., paints, enamels, or TiO2 suspensions, using various techniques. The third group is cement mortars with a thick layer of photoactive concrete on the top. In addition, methods for determining the photoactivity of cement composites, mechanical properties, and physicochemical parameters of such materials are briefly presented. Finally, examples of investments with the use of photoactive cements and development prospects are shown.
“…In general, mortars with a higher sand content (1:2) showed reduced resistance to carbonation and water absorption, which was consistent with the previous research by Huang et al [ 157 ], which showed that CO 2 gas penetrates the concrete surface through the sand-cement gap [ 157 ]. This means that increasing the volume of sand in concrete also increases CO 2 penetration [ 158 ]. Duan et al [ 156 ] noted an improvement in carbonation resistance by 77%, 62%, and 42% for fluidized bed fly ash geopolymer paste samples containing 1%, 3%, and 5% NT, respectively, after 180 days of exposure.…”
Section: Results Of Mechanical Properties Of Modified Cement Mortarsmentioning
This article presents a short overview of modified cements with photocatalytic activity. First, the types and three main methods of obtaining photoactive cements are presented. The most frequently used modification method is the incorporation of a photocatalyst into the total mass of the cement. The second group analyzed is cements obtained by applying a thin layer of photoactive materials, e.g., paints, enamels, or TiO2 suspensions, using various techniques. The third group is cement mortars with a thick layer of photoactive concrete on the top. In addition, methods for determining the photoactivity of cement composites, mechanical properties, and physicochemical parameters of such materials are briefly presented. Finally, examples of investments with the use of photoactive cements and development prospects are shown.
“…In this expression, j 1 (a) is the value of the mass flow of chloride ions passing through the plane situated at "a" distance x = a; ρ 1 1 , ρ 1 2 , and ρ 1 n are the averaged mass densities of ion Cl − at the midpoints of consecutive intervals (0, g), (g, 2g), . .…”
Section: Migration Studies and Determination Of Diffusion Coefficient...mentioning
confidence: 99%
“…Depending on their location and function, building structures are exposed to many harmful factors. The most common causes of reinforcement corrosion and concrete damage are carbonation and chloride penetration [ 1 ]. The faster the carbon dioxide or chlorides penetrate the concrete, the faster the passive layer on the rebar is destroyed and the corrosion process begins [ 2 ].…”
This study presents a comparison of the protective properties of three concretes of similar composition on the effect of chloride ions. To determine these properties, the values of the diffusion and migration coefficients of chloride ions in concrete were determined using both standard methods and the thermodynamic ion migration model. We tested a comprehensive method for checking the protective properties of concrete against chlorides. This method can not only be used in various concretes, even those with only small differences in composition, but also in concretes with various types of admixtures and additives, such as PVA fibers. The research was carried out to address the needs of a manufacturer of prefabricated concrete foundations. The aim was to find a cheap and effective method of sealing the concrete produced by the manufacturer in order to carry out projects in coastal areas. Earlier diffusion studies showed good performance when replacing ordinary CEM I cement with metallurgical cement. The corrosion rates of the reinforcing steel in these concretes were also compared using the following electrochemical methods: linear polarization and impedance spectroscopy. The porosities of these concretes, determined using X-ray computed tomography for pore-related characterization, were also compared. Changes in the phase composition of corrosion products occurring in the steel–concrete contact zone were compared using scanning electron microscopy with a micro-area chemical analysis capability, in addition to X-ray microdiffraction, to study the microstructure changes. Concrete with CEM III cement was the most resistant to chloride ingress and therefore provided the longest period of protection against chloride-initiated corrosion. The least resistant was concrete with CEM I, for which, after two 7-day cycles of chloride migration in the electric field, steel corrosion started. The additional use of a sealing admixture can cause a local increase in the volume of pores in the concrete, and at the same time, a local weakening of the concrete structure. Concrete with CEM I was characterized as having the highest porosity at 140.537 pores, whereas concrete with CEM III (characterized by lower porosity) had 123.015 pores. Concrete with sealing admixture, with the same open porosity, had the highest number of pores, at 174.880. According to the findings of this study, and using a computed tomography method, concrete with CEM III showed the most uniform distribution of pores of different volumes, and had the lowest total number of pores.
“…The number and size of the cracks increase the permeability of concrete, which is one of the critical parameters reducing its durability [12]. Chloride ions, carbon dioxide and oxygen dissolved in water lead to corrosion on the rebar, resulting in potential structural failures [13][14][15]. Therefore, many traditional maintenance and fixing methods have been implemented to avoid this type of degradation.…”
Concrete is commonly used as a supporting material in the construction industry. Although it can withstand heavy loads, it is very brittle and sensitive to crack formation. Earthquakes and other environmental factors may result in the formation of cracks in the concrete structure. Penetration of chloride and atmospheric water with dissolved oxygen and carbon dioxide gasses through these cracks leads to corrosion of rebar (reinforcing steel bars). This paper is a short review of polymeric structures as concrete healing materials.
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