Photoluminescence spectra have been investigated for LP€-grown AI,Gal-,Sb at 77 K, and five emission peaks observed. These emissions have been interpreted by taking into account one shallow acceptor level and two native defect levels in the energy band diagram. The shallow acceptor level is located at about 30 meV above the valence band, which may be due to the complex defect VGaGaSb.The native defects introduce two levels, which are about 90 meV below the rl minimum and about 160 meV below the Ll minimum. The defect levels may be related to complex defects of the Sb vacancy.