2005
DOI: 10.1016/j.jcis.2004.11.065
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Calculation of the electric polarizability of a charged spherical dielectric particle by the theory of colloidal electrokinetics

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Cited by 56 publications
(61 citation statements)
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“…Counterions are more mobile in the diffuse layer than in the Stern layer, and contribute separately to the overall magnitude of K s and thus to the DEP behavior of nanoparticles. [28][29][30][31] A comprehensive study of the ac and dc electrokinetic properties of latex nanoparticles, as a function of suspending medium conductivity and viscosity, has been reported by Ermolina and Morgan, 32 and a theoretical modeling of the DEP force that takes into account the influence of the electrical double layer has been presented by Zhou et al 33 Analysis of the normal and tangential ionic currents that occur around and at the surface of a particle, when its diameter approaches and becomes smaller than the width of its own electrical double layer, indicates that a capacitance effect contributes to the total polarizability of the particle, and exceeds the influence of the surface conductance K s . 34,35 Basuray and Chang 34 also showed that the DEP cross-over frequency for nanocolloids is inversely proportional to the RC time constant of the diffuse layer component of the electrical double layer.…”
Section: ͑15͒mentioning
confidence: 99%
“…Counterions are more mobile in the diffuse layer than in the Stern layer, and contribute separately to the overall magnitude of K s and thus to the DEP behavior of nanoparticles. [28][29][30][31] A comprehensive study of the ac and dc electrokinetic properties of latex nanoparticles, as a function of suspending medium conductivity and viscosity, has been reported by Ermolina and Morgan, 32 and a theoretical modeling of the DEP force that takes into account the influence of the electrical double layer has been presented by Zhou et al 33 Analysis of the normal and tangential ionic currents that occur around and at the surface of a particle, when its diameter approaches and becomes smaller than the width of its own electrical double layer, indicates that a capacitance effect contributes to the total polarizability of the particle, and exceeds the influence of the surface conductance K s . 34,35 Basuray and Chang 34 also showed that the DEP cross-over frequency for nanocolloids is inversely proportional to the RC time constant of the diffuse layer component of the electrical double layer.…”
Section: ͑15͒mentioning
confidence: 99%
“…To capture target cells without losing, we calculated the maximum flow rate that we will use in experiments. To estimate the flow rate, first, we calculated the DEP force on a 20µm diameter cell (or bead) in the z direction along the contour A-B (" Figure. 2 ) , and calculated the DEP force using equation (1) and plotted in " Figure. 3(c)" [18][19][20]. For more stringent conditions, we have calculated the critical dimensions of the device needed to capture the cells that are about 400 µm above the electrodes.…”
Section: Design and Fabrication Of Microfluidics Channelsmentioning
confidence: 99%
“…This accelerates the ion transport mechanisms and results in the electrolysis process at the solid/solution interface where O 2 is produced at the anode and H 2 is produced at the cathode. These processes occur at a potential limit that depends on the electrode materials [5][6][7][8][9][10][11] …”
Section: A Electrical Properties Ofwatermentioning
confidence: 99%
“…At higher frequencies, a reversible faradic process may occurs via charge transfer at the interface (oxide formation and reduction) in addition adsorption and desorption of water ions. Since the polarity alteration of the electrodes must cycle rapidly at some resonant frequency, a reversible electrode process is necessary whereas, in the case of an irreversible process, the alternating potential would result in the accumulation of solids or gasses onto the electrode surface overtime [5][6][7][8][9][10][11].…”
Section: B Feeding Processmentioning
confidence: 99%