Bulk and solution properties of a thermo-responsive rod–coil block polymer based on poly(N-isopropylacrylamide)

Liu, Peng; Liang, Jiexing; Shen, Chen; Zhang, Hai-Liang

doi:10.1039/c4ra07179d

Cited by 5 publications

(2 citation statements)

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“…[33][34][35][36] To date, perhaps the most extensively studied thermosensitive hybrid nanoparticles have been coated with poly(N-isopropylacrylamide) (PNIPAM) brushes, which exhibit LCST at $32 C, close to body temperature. [37][38][39][40] Wang and colleagues 41 synthesised SiO 2 nanoparticles graed with PNIPAM shells by surface-initiated ATRP in aqueous solution, using CuCl/bpy as a catalytic system. Despite its widespread popularity in materials science, PNIPAM has narrow and low LCST, which limits its practical applications.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of hybrid silica nanoparticles grafted with thermoresponsive poly(ethylene glycol) methyl ether methacrylate via AGET-ATRP

Sun

Tai

et al. 2015

RSC Adv.

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Section: Introductionmentioning

confidence: 99%

Synthesis of hybrid silica nanoparticles grafted with thermoresponsive poly(ethylene glycol) methyl ether methacrylate via AGET-ATRP

Sun

Tai

et al. 2015

RSC Adv.

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“…A number of review articles are available for the self‐assembly of rod‐coil BCPs based on mesogen‐jacketed LC polymers and main‐chain LC polymers . In recent years, side‐chain liquid crystalline polymers (SCLCPs) have been incorporated into rod‐coil BCPs, which show unique self‐assembly behavior in solution . In addition, BCPs containing stimuli‐responsive SCLCPs render their assemblies potential applications in controllable drug release, optoelectronic devices, and so forth.…”

Section: Self‐assembly Of Amphiphilic Rod‐coil Linear Block Copolymersmentioning

confidence: 99%

Recent advances in the solution self‐assembly of amphiphilic “rod‐coil” copolymers

Huang

et al. 2017

J. Polym. Sci. Part A: Polym. Chem.

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Solution self‐assembly of amphiphilic “rod‐coil” copolymers, especially linear block copolymers and graft copolymers (also referred to as polymer brushes), has attracted considerable interest, as replacing one of the blocks of a coil‐coil copolymer with a rigid segment results in distinct self‐assembly features compared with those of the coil‐coil copolymer. The unique interplay between microphase separation of the rod and coil blocks with great geometric disparities can lead to the formation of unusual morphologies that are distinctly different from those known for coil‐coil copolymers. This review presents the recent achievements in the controlled self‐assembly of rod‐coil linear block copolymers and graft copolymers in solution, focusing on copolymer systems containing conjugated polymers, liquid crystalline polymers, polypeptides, and polyisocyanates as the rod segments. The discussions concentrate on the principle of controlling over the morphology of rod‐coil copolymer assemblies, as well as their distinctive optical and optoelectronic properties or biocompatibility and stimuli‐responsiveness, which afford the assemblies great potential as functional materials particularly for optical, optoelectronic and biological applications. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 1459–1477

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Synthesis and solution properties of novel thermo- and pH-responsive poly(N-vinylcaprolactam)-based linear–dendritic block copolymers

Tang

et al. 2016

RSC Adv.

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Bulk and solution properties of a thermo-responsive rod–coil block polymer based on poly(N-isopropylacrylamide)

Abstract: Molecular weight dependence on thermoresponsive behaviors of rod–coil diblock copolymers (x indicates the DP of rod PHIPPVTA blocks).

Cited by 5 publications

References 64 publications

Synthesis of hybrid silica nanoparticles grafted with thermoresponsive poly(ethylene glycol) methyl ether methacrylate via AGET-ATRP

Synthesis of hybrid silica nanoparticles grafted with thermoresponsive poly(ethylene glycol) methyl ether methacrylate via AGET-ATRP

Recent advances in the solution self‐assembly of amphiphilic “rod‐coil” copolymers

Synthesis and solution properties of novel thermo- and pH-responsive poly(N-vinylcaprolactam)-based linear–dendritic block copolymers

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