1998
DOI: 10.1021/la980386f
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Building and Manipulating Three-Dimensional and Linked Two-Dimensional Structures of Nanoparticles Using Scanning Force Microscopy

Abstract: Manipulation of nanoparticles with the scanning force microscope (SFM) has been limited until now to clearing areas on a surface or to moving single particles sequentially to create two-dimensional patterns. The research reported here uses a previously described setup for nanomanipulation with the SFM to (i) build a simple three-dimensional pyramidal structure by pushing a nanoparticle on top of two others and (ii) rotate and translate a linked two-particle structure. The experiments are conducted in air and a… Show more

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Cited by 78 publications
(36 citation statements)
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“…We have demonstrated two variants of this approach: 1) first deposit the particles, position them, and then immerse the sample in the di-thiol solution to link them or 2) deposit the particles, apply the thiols, and then manipulate the particles into contact, thus linking them. We also have shown that it is possible to push a group of nanoparticles linked by di-thiols as a whole [54], [55]. These results demonstrate hierarchical assembly at the nanoscale, i.e., the construction of assemblies of components, which are themselves (sub-) assemblies of other components or of primitive building blocks.…”
Section: E Linking and Embeddingmentioning
confidence: 53%
See 1 more Smart Citation
“…We have demonstrated two variants of this approach: 1) first deposit the particles, position them, and then immerse the sample in the di-thiol solution to link them or 2) deposit the particles, apply the thiols, and then manipulate the particles into contact, thus linking them. We also have shown that it is possible to push a group of nanoparticles linked by di-thiols as a whole [54], [55]. These results demonstrate hierarchical assembly at the nanoscale, i.e., the construction of assemblies of components, which are themselves (sub-) assemblies of other components or of primitive building blocks.…”
Section: E Linking and Embeddingmentioning
confidence: 53%
“…We have investigated several approaches to linking. The first uses covalent (i.e., chemical) bonding to a linker [54], [55]. For example, gold particles can be connected with di-thiols.…”
Section: E Linking and Embeddingmentioning
confidence: 99%
“…The probe tip can also be used to grab weakly adsorbed molecules or small particles from a surface, and transfer them to another region of the same substrate to generate highly ordered structures. [14] However, this strategy seems to be less frequently used than the former one because the grabbing, moving, and unloading steps can be slow and hard to control.…”
Section: Writing With a Rigid Stylusmentioning
confidence: 99%
“…In addition to the imaging mode, an operator can command the motion of the AFM tip in an arbitrary manner, thus to manipulate nanoscale objects with nanoscale precision. Since the first try using AFM to manipulate nano-objects [2], many research groups have been working on AFM-based nanomanipulation [3]- [7]. Tasks such as pushing, pulling, cutting, bending, kinking, rolling, and sliding have been reported in the literature [3]- [6], [8]- [10].…”
Section: Introductionmentioning
confidence: 99%