Using methods from algebraic graph theory and convex optimization, we study the relationship between local structural features of a network and spectral properties of its Laplacian matrix. In particular, we derive expressions for the so-called spectral moments of the Laplacian matrix of a network in terms of a collection of local structural measurements. Furthermore, we propose a series of semidefinite programs to compute bounds on the spectral radius and the spectral gap of the Laplacian matrix from a truncated sequence of Laplacian spectral moments. Our analysis shows that the Laplacian spectral moments and spectral radius are strongly constrained by local structural features of the network.On the other hand, we illustrate how local structural features are usually not enough to estimate the Laplacian spectral gap.