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Khirade, P. W.; Chaudhari, Ajay; Shinde, J.; Helambe, S. N.; Mehrotra, S. C.

doi:10.1023/a:1022666128166

Cited by 59 publications

(15 citation statements)

References 10 publications

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“…This suggests that the intermolecular association is taking place in all these systems. Similar results were reported by Khirade et al, 18 for DMF-alcohol mixtures. It can be seen from Tables 1-6 that, the values of e o and e ∞ for pure alcohols and amides and binary mixtures of alcohols with amides are in the order:…”

Section: Resultssupporting

confidence: 92%

“…Patil et al 17 reported the dielectric parameters for aniline -alcohol mixtures using the time domain technique. Dielectric parameters for dimethylsulphoxide-alcohol and dimethylformamide -alcohol mixtures were reported by Khirade et al 18,19 using TDR. Chaudari and Mehrotra 20 reported the dielectric parameters for pyridine-alcohol mixtures using time domain reflectometry.…”

Section: Introductionmentioning

confidence: 99%

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Relaxation Study of N-Submitted Amides with Alcohol Mixtures by Time Domain Reflectometry

Arunkumar¹,

Ramachandran²,

Samuvel³

2016

Orient. J. Chem

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Using Time Domain Reflectometry (TDR), dielectric relaxation studies have been carried out on binary mixtures of amides (N-methylacetamide, N,N-dimethylacetamide with alcohols (1-butanol, 1-pentanol) for various concentrations over the frequency range from 10 MHz to 10 GHz at 303 K. The Kirkwood correlation factor and excess dielectric constant properties were determined and discussed to yield information on the molecular interactions of the systems. The relaxation time is vary with the chain length of alcohols and substituted amides are noticed. The Bruggeman plot shows a deviation from linearity. This deviation was attributed to some sort of molecular interaction which may take place between the alcohols and substituted amides. The excess static permittivity and excess inverse relaxation time values vary from negative to positive for all the systems indicating the solute-solvent interaction to exist between alcohols and substituted amides for all the dynamics of the mixture.

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Section: Resultssupporting

confidence: 92%

Section: Introductionmentioning

confidence: 99%

Relaxation Study of N-Submitted Amides with Alcohol Mixtures by Time Domain Reflectometry

Arunkumar¹,

Ramachandran²,

Samuvel³

2016

Orient. J. Chem

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“…There is formation of multimers and dimers. Earlier in [28][29][30][31], ε E was evaluated to confirm the formation of multimers and their nature in different binary mixtures of associating polar molecules. Figure 4 shows the plot of excess permittivity against molar fraction of FA for all temperatures.…”

Section: Resultsmentioning

confidence: 99%

Dielectric studies on binary mixtures of formamide with ethanolamine using the time domain technique

Undre¹,

Khirade²,

Jagdale³

et al. 2011

Lith. J. Phys.

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Dielectric relaxation measurements on formamide (FA) -ethanolamine (ETA) solvent mixtures have been carried out across the entire concentration range using time domain reflectometry technique at 15, 25, 35, and 45• C over the frequency range from 10 MHz to 10 GHz. The mixtures exhibit a principle dispersion of the Davidson-Cole relaxation type at microwave frequencies. Bilinear calibration method is used to obtain complex permittivity ε * (ω) from complex reflection coefficient ρ * (ω) over the frequency range 10 MHz to 10 GHz. The excess permittivity ε E , excess inverse relaxation time (1/τ ) E , Kirkwood correlation factor g eff , and thermodynamic parameters such as Gibbs energy of activation ∆G and molar enthalpy of activation ∆H are also calculated to study the solute-solvent interaction.

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“…Different techniques have been used to investigate the dielectric, thermodynamic and optical properties of monoalkylethers of ethylene glycol in pure as well as mixed solvents [1][2][3][4][5][6][7][8][9][10][11][12][13][14]. These properties were attributed as existence of inter and intra molecular hydrogen bonding in EE.…”

Section: -Ethoxyethanol [Ee]mentioning

confidence: 99%

Dielectric relaxation study of aqueous 2-ethoxyethanol using time domain reflectometry technique

Joshi¹,

Hudge

Kumbharkhane

2011

Indian J Phys

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The complex permittivity spectra of 2-ethoxyethanol in water solutions have been studied at different concentrations and temperatures using a picosecond time domain reflectometry technique. The complex dielectric permittivity spectrum of 2-ethoxyethanol shows Cole-Davidson type behavior. Increase in dielectric relaxation time may be due to increase in hetero molecular interaction strength. Minimum in Excess dielectric constant values provides the information about stable complex adduct. The Kirkwood correlation factor, thermodynamic properties and Bruggeman factor have also been determined and the results are interpreted in terms of hydrogen bonding and interactions among the solute -solvent molecules.

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Untitled

Cited by 59 publications

References 10 publications

Relaxation Study of N-Submitted Amides with Alcohol Mixtures by Time Domain Reflectometry

Relaxation Study of N-Submitted Amides with Alcohol Mixtures by Time Domain Reflectometry

Dielectric studies on binary mixtures of formamide with ethanolamine using the time domain technique

Dielectric relaxation study of aqueous 2-ethoxyethanol using time domain reflectometry technique

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