2010
DOI: 10.23939/chcht04.04.325
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Bitumen Production via Tar Oxidation in the Presence of Petroleum Resin with Fluorine-Containing Groups

Abstract: The tar oxidation process has been studied at 523 K, air flow rate of 2.0; 2.5 and 5.0 h-1 and process time of 6, 9 and 12 h in the presence of 2.5; 5.0 and 7.5 mas % (to calculate for the raw material)of petroleum resin with fluorine atoms. The tar is the residue of black oil vacuum distillation obtained from the oils of Western-Ukrainian fields. The effect of process conditions on the characteristics of obtained bitumen has been determined. The structural-group composition of blown bitumen has been examined.

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Cited by 11 publications
(3 citation statements)
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“…The object is the bitumen BN 70/30 GOST 6617-76 RF, a petroleum resin obtained by thermal polymerization of C9 fraction of liquid pyrolysis products (plant "Slanci", Saint-Petersburg, Russia) TU 2451-024-78780418-2006 and oxidized with peracetic acid [4], which is formed in situ and is used as a modifier. The oxidation of the petroleum resin allows inclusion into the structure of the molecule of up to 13 % of epoxide groups, which later on will intensify the process of the composition condensation by macromolecular crosslinking [3,5]. Tetrabutoxytitanium (tetrabutilate titanium, TBT) -butyl orthotitanic acid -(C 4 H 9 O) 4 Ti was used as a hardening agent.…”
Section: Methodsmentioning
confidence: 99%
“…The object is the bitumen BN 70/30 GOST 6617-76 RF, a petroleum resin obtained by thermal polymerization of C9 fraction of liquid pyrolysis products (plant "Slanci", Saint-Petersburg, Russia) TU 2451-024-78780418-2006 and oxidized with peracetic acid [4], which is formed in situ and is used as a modifier. The oxidation of the petroleum resin allows inclusion into the structure of the molecule of up to 13 % of epoxide groups, which later on will intensify the process of the composition condensation by macromolecular crosslinking [3,5]. Tetrabutoxytitanium (tetrabutilate titanium, TBT) -butyl orthotitanic acid -(C 4 H 9 O) 4 Ti was used as a hardening agent.…”
Section: Methodsmentioning
confidence: 99%
“…To improve the adhesive properties of bitumen it is proposed to use the functional resins. [8][9][10][11][12][13][14][15] The peculiarity is that the resins contain different by nature functional groups (epoxy, peroxy, hydroxy, etc.) in their structure, which may react with bitumen component and form the cross-linked structures.…”
Section: Introductionmentioning
confidence: 99%
“…Last decades the scientific researchers of the Department of Chemical Technology of Oil and Gas Processing at Lviv Polytechnic National University have been conducting studies on possibility of using petroleum [12][13][14], phenol-formaldehyde [15], epoxy [16], coumarone-indene [17] and phenol-cresol-formaldehyde [18][19][20][21][22] resins as polymeric additives.…”
Section: Introductionmentioning
confidence: 99%