Bis[μ-2-methoxy-<i>N</i>′-(2-oxidobenzoyl)benzohydrazidato(3–)]dipyridinetrizinc(II)

Yu, Zongxue; Sun, Yuxi

doi:10.1107/s1600536806050094

Cited by 3 publications

(1 citation statement)

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“…Each pyridine molecule acts as a monodentate ligand through the N atom. The structure of the compound is similar to that of the zinc(II) compound we reported recently [10]. The average coordinate bond lengths are 1.940(3) Å .…”

Section: Resultsmentioning

confidence: 51%

Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II)

Liang

Wang

et al. 2008

Struct Chem

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A novel homotrinuclear pyridine Schiff base copper(II) compound, [Cu 3 (C 15 H 11 N 2 O 4 ) 2 (C 5 H 5 N) 2 ], has been synthesized and characterized by elemental analysis and X-ray single crystal deterimination. X-ray structural determination reveals that each copper(II) ion has a distorted square-planar geometry. The central copper ion is coordinated by two O and two N atoms from two Schiff base ligands, while each terminal copper ion is coordinated by one N and two O atoms of one Schiff base ligand and by one N atom of a pyridine molecule. Density funcational theory (DFT) method calculations of the structure, atomic charges distribution and natural bond orbital (NBO) analyses have been performed. The coordinate stabilization energies show that the trinuclear copper(II) compound is very stable.

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Section: Resultsmentioning

confidence: 51%

Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II)

Liang

Wang

et al. 2008

Struct Chem

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Trapping of a Four‐Coordinate Zinc Salphen Complex Inside a Crystal Matrix

Escudero‐Adán

Benet‐Buchholz

Kleij

2009

Chemistry A European J

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A remarkable twosome: Four-coordinate square-planar complexes based on [Zn(salen)] derivatives are conveniently captured inside a crystal matrix using a supramolecular protecting strategy (see figure). The four-coordinate species is accompanied by a five-coordinate complex that binds an axial ligand able to hydrogen bond to an N-heterocycle positioned in the axial region of the coordinative unsaturated derivative. The size of the N-heterocycle is a decisive stabilization parameter.

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Metal-Based Molecular Chains: Design by Coordination Chemistry

Aromı́

2011

Comments on Inorganic Chemistry

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Bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3–)]dipyridinetrizinc(II)

Abstract: Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.007 Å R factor = 0.050 wR factor = 0.132 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see

Cited by 3 publications

References 8 publications

Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II)

Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II)

Trapping of a Four‐Coordinate Zinc Salphen Complex Inside a Crystal Matrix

Metal-Based Molecular Chains: Design by Coordination Chemistry

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