Bis[N-(8-quinolyl)pyridine-2-carboxamidato]iron(III) perchlorate monohydrate

Abstract

Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.006 Å; R factor = 0.054; wR factor = 0.140; data-to-parameter ratio = 13.5. CommentComplexes containing carbonyl amine (organic amide) ligands have been the interest of chemists due to their potential applications, such as in catalysis, optics, information storage, medicine, molecular electrochemistry, biochemistry and biolo-

New Copper (II) Isomer Based on 8-aminoquinoline Ligand: Synthesis, Molecular Structure, Hirshfeld Surface Analysis and Computational Study.

“…The Cu-N bond lengths range from 2.007 (2) to 2.023 (2) Å (Table 2). These bond lengths are like those observed in similar structures containing 8-aminoquinoline ligands [27][28][29]. The axial Cu-OW1 bond (2.431(17) Å) is remarkably longer than the equatorial Cu-N distances (Table 2) because of the Jahn-Teller effect [30].…”

A Novel CuII/8-Aminoquinoline Isomer Complex [Cu(H2O)2(C9H8N2)2]Cl2: Solvothermal Synthesis, Molecular Structure, Hirshfeld Surface Analysis, and Computational Study

“…The Cu-N bond lengths range from 2.007 (2) to 2.023 (2) Å (Table 2). These bond lengths are like those observed in similar structures containing 8-aminoquinoline ligands [42][43][44]. The axial Cu-OW1 bond (2.431(17) Å) is remarkably longer than the equatorial Cu-N distances (Table 2) because of the Jahn-Teller effect [45].…”