Bipolar Electrochemistry: A Powerful Tool for Electrifying Functional Material Synthesis

Shida, Naoki; Zhou, Yaqian; Inagi, Shinsuke

doi:10.1021/acs.accounts.9b00337

Cited by 152 publications

(108 citation statements)

References 79 publications

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“…Among the many effective approaches, electrochemical reduction of CO 2 has unmatched advantages, such as mild operating conditions, usage of renewable electricity as the energy input and feasibility for modular manufacturing to match the distributed availability of CO 2 feedstocks. [15][16][17][18][19][20][21] At present, the commercialization of CO 2 electroreduction reaction is mainly obstructed by the high cost, low selectivity, high overpotential and poor stability of the catalyst. [22][23][24][25][26][27][28][29] Among the numerous catalyst materials that were studied, indium (In) was found to be selective towards the production of formate.…”

Section: Introductionmentioning

confidence: 99%

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts

Zhu

Han

2020

ChemCatChem

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Electrochemical reduction of CO2 (CO2RR) is a promising solution to mitigate the ever‐increasing global carbon emission. Indium‐based catalysts have been extensively studied for catalyzing the production of formate, CO, and even multi‐carbon molecules from CO2. Rational design of the catalyst, however, is urgently needed to further improve the activity, selectivity, and stability for the sake of commercialization. Herein, we comprehensively reviewed recent progresses on the indium based CO2RR catalysts. Specifically, aspects regarding the nature of active sites, reaction mechanism, and the impact of operating conditions are overviewed. The reported indium‐based monometallic and bimetallic catalysts in the literature are summarized, as well. Future directions should be focused on the understanding of catalyst system during the reaction and under industrial‐relevant conditions.

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Section: Introductionmentioning

confidence: 99%

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts

Zhu

Han

2020

ChemCatChem

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“…The opposite direction of the bipolar electrode poles with the feeding electrodes polarity is an important key parameter in the process. [ 100,102 ] This technique has been evaluated for a large variety of applications such as electronic device fabrications, electrochemical sensing, and electrodeposition. [ 97 ] Recently, this method has been employed for the exfoliation of 2D materials such as graphene, [ 103–105 ] molybdenum diselenide (MoSe 2 ), [ 106 ] tungsten disulfide (WS 2 ), [ 107 ] and hexagonal boron nitride (hBN).…”

Section: Liquid‐based Exfoliation Of Bpmentioning

confidence: 99%

Liquid‐Based Exfoliation of Black Phosphorus into Phosphorene and Its Application for Energy Storage Devices

et al. 2021

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Black phosphorus (BP) as a rising star among 2D materials has attracted attention for a wide range of applications due to its fascinating properties. The key point for the real application of phosphorene depends on its exfoliation technique to produce high‐quality nanosheets. In recent years, tremendous efforts have been made in the preparation and energy storage application of phosphorene and phosphorene‐based hybrid electrodes. Herein, the state‐of‐the‐art liquid‐based exfoliation and characterization of phosphorene fabricated by sonication, anodic and cathodic electrochemical exfoliation, and bipolar electrochemical exfoliation in diverse solutions and conditions are discussed. In addition, the electrochemical properties and storage mechanism of phosphorene‐based electrodes for rechargeable batteries and supercapacitors are discussed. Finally, the challenges and opportunities of phosphorene nanosheets in terms of exfoliation and energy storage applications are addressed.

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“…For example, a copper wire, used as a bipolar electrode (BPE), can be propelled in folded channels with different angles (from 30° to 180°) due to the asymmetric formation of hydrogen bubbles at the cathodic side [52] . For a more detailed description of this technique the reader is invited to consult other publications [53–57] …”

Section: Motion‐driven By Electrochemistrymentioning

confidence: 99%

Electrochemistry‐Based Light‐Emitting Mobile Systems

et al. 2020

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Light‐emitting mobile systems are presented as an important concept for direct visualization and tracking of active objects. Motion or light emission can be achieved by different electrochemical mechanisms. Various devices, that generate light by fluorescence, (electro)chemiluminescence or via light emitting diodes are shown to be an interesting alternative for the detection or release of target molecules, providing straightforward optical imaging. This review summarizes and discusses the recent advances with respect to the design and the potential applications of such original systems.

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Bipolar Electrochemistry: A Powerful Tool for Electrifying Functional Material Synthesis

Cited by 152 publications

References 79 publications

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts

Liquid‐Based Exfoliation of Black Phosphorus into Phosphorene and Its Application for Energy Storage Devices

Electrochemistry‐Based Light‐Emitting Mobile Systems

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Bipolar Electrochemistry: A Powerful Tool for Electrifying Functional Material Synthesis

Cited by 152 publications

References 79 publications

Recent Advances in Electrochemical CO2 Reduction on Indium‐Based Catalysts

Recent Advances in Electrochemical CO2 Reduction on Indium‐Based Catalysts

Liquid‐Based Exfoliation of Black Phosphorus into Phosphorene and Its Application for Energy Storage Devices

Electrochemistry‐Based Light‐Emitting Mobile Systems

Contact Info

Product

Resources

About

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts

Recent Advances in Electrochemical CO₂ Reduction on Indium‐Based Catalysts