2019
DOI: 10.1021/acssuschemeng.9b04210
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Biodegradable Elastomer from 2,5-Furandicarboxylic Acid and ε-Caprolactone: Effect of Crystallization on Elasticity

Abstract: Most biodegradable thermoplastic materials cannot be used as elastomers due to their relatively poor elasticity. Poly­(butylene furandicarboxylate-co-ε-caprolactone) (PBFCL) copolyesters were synthesized from 2,5-furandicarboxylic acid (FDCA), 1,4-butanediol, and poly­(ε-caprolactone) diols. The PBFCLs are susceptible to hydrolysis and enzyme degradation, and the degradation rate could be controlled by the enzymes. PBFCL40 and PBFCL50 (CL molar content) displayed high tensile strength (≥50 MPa), good elongatio… Show more

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Cited by 41 publications
(43 citation statements)
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References 53 publications
(89 reference statements)
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“…Lanthanum(III) acetylacetonate [ 73 , 79 ], polyphosphoric acid [ 72 ], cobalt acetate [ 41 ], dibutyltin oxide [ 33 , 68 ], and EG antimony [ 48 ] have also occasionally been used. Additives, mainly Irganox 1010, a sterically hindered phenolic primary radical scavenger common in the synthesis of many types of polymers, are periodically used as antioxidants and heat stabilizers [ 48 , 56 , 58 , 85 , 91 ].…”
Section: Synthesis Molecular Weight and Randomness Of Fdca-basedmentioning
confidence: 99%
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“…Lanthanum(III) acetylacetonate [ 73 , 79 ], polyphosphoric acid [ 72 ], cobalt acetate [ 41 ], dibutyltin oxide [ 33 , 68 ], and EG antimony [ 48 ] have also occasionally been used. Additives, mainly Irganox 1010, a sterically hindered phenolic primary radical scavenger common in the synthesis of many types of polymers, are periodically used as antioxidants and heat stabilizers [ 48 , 56 , 58 , 85 , 91 ].…”
Section: Synthesis Molecular Weight and Randomness Of Fdca-basedmentioning
confidence: 99%
“…Finally, vacuum is applied, and the temperature is increased for the polycondensation step. On the other hand, polylactide (PLA) or poly(ε-caprolactone) (PCL) oligomers can be prepared separately and added directly in a two-stage polymerization reaction [ 35 , 62 , 85 ].…”
Section: Synthesis Molecular Weight and Randomness Of Fdca-basedmentioning
confidence: 99%
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