“…Subsequent total elemental analysis was carried out by inductively coupled plasma mass spectrometry (ICP-MS; Agilent 7500cx, Santa Clara, USA) using (i) collision cell mode (helium gas) for Li, Be, B, Na, Mg, Al, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Sb, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Tl, Pb, Bi, Th and U; and (ii) hydrogen reaction cell mode for Si and Se (Hamilton et al 2015;. Iodine analyses were undertaken separately owing to the requirement for an alkaline extraction with tetramethylammonium hydroxide (TMAH).…”