A hole transporting material based on triphenylamine with high glass transition temperature (T g ) of 99 o C, coded as BT41, was synthesized and applied to perovskite solar cell. The pristine BT41 showed low power conversion efficiency (PCE) of 1.1% due to low photocurrent density (J sc ) of ca. 6 mA/cm 2 and almost negligible fill factor of less than 0.2, which however significantly improved to 9.0% owing to mainly 3-times improved J sc of 17.6 mA/cm 2 by adding both tert-butylpyridine (tBP) and lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) as additives. Oxidation of BT41 was dominated by LiTFSI, which is responsible for the one order of magnitude increased hole mobility. Additive addition also reduced recombination resistance, which correlates to the higher fill factor. Although both additives in BT41 contributed cooperatively to improvement of photovoltaic performance, LiTFSI played major role in the enhancement.