The method described in Part I [Phys. Fluids 31, XXXX (1988)] is extended to treat the problem of determining the permeability of random arrays of infinitely long cylinders. The results for the transverse and longitudinal permeabilities averaged over several configurations of random arrays of cylinders are presented as a function of the area fraction of the cylinders. A detailed comparison is made with the estimates of the permeability obtained by various approximate and asymptotic theories to determine their range of validity.
Cold plasma has become an attractive tool for promoting wound healing and treating skin diseases. This article presents an atmospheric pressure plasma jet (APPJ) generated in argon gas through dielectric barrier discharge, which was applied to superficial skin wounds in BALB/c mice. The mice (n = 50) were assigned randomly into five groups (named A, B, C, D, E) with 10 animals in each group. Natural wound healing was compared with stimulated wound healing treated daily with APPJ for different time spans (10, 20, 30, 40, and 50 seconds) on 14 consecutive days. APPJ emission spectra, morphological changes in animal wounds, and tissue histological parameters were analyzed. Statistical results revealed that wound size changed over the duration of the experimental period and there was a significant interaction between experimental day and group. Differences between group C and other groups at day 7 were statistically significant (p < 0.05). All groups had nearly achieved closure of the untreated control wounds at day 14. The wounds treated with APPJ for 10, 20, 30, and 40 seconds showed significantly enhanced daily improvement compared with the control and almost complete closure at day 12, 10, 7, and 13, respectively. The optimal results of epidermal cell regeneration, granulation tissue hyperplasia, and collagen deposition in histological aspect were observed at day 7. However, the wounds treated for 50 seconds were less well healed at day 14 than those of the control. It was concluded that appropriate doses of cold plasma could inactivate bacteria around the wound, activate fibroblast proliferation in wound tissue, and eventually promote wound healing. Whereas, over doses of plasma suppressed wound healing due to causing cell death by apoptosis or necrosis. Both positive and negative effects may be related to the existence of reactive oxygen and nitrogen species (ROS and RNS) in APPJ.
The problem of determining the bulk or effective thermal conductivity of a two-phase composite material whose unit cells contain N(N>1) spherical particles of thermal conductivity αk suspended in a medium of thermal conductivity k has been treated by extending an earlier analysis of McPhedran and Milton [Appl. Phys. A 26, 207 (1981)] who considered the case N=1. The technique is applied to computer-generated two-phase composites with N=16 whose radial distribution functions approximately satisfy the Percus–Yevick equation. The results, which are presented for a wide range of α and φ (the volume fraction of the spheres), are shown to be in good agreement with the experimental values of conductivity of fluidized beds reported by Turner [Chem. Eng. Sci. 31, 487 (1976)].
Several phosphorescent Ir III ppy-type complexes (ppy ¼ 2-phenylpyridine anion) bearing dimesitylboron (B(Mes) 2 ) units have been designed and some of them have been newly prepared. By changing the substitution positions with different electronic characters that can manipulate the electron-accepting ability of the attached B(Mes) 2 moieties, the direction of the metal-to-ligand charge transfer (MLCT) process for these Ir III complexes can be either retained or shifted, which can provide a new strategy toward phosphorescent color tuning. Through computational studies, shifting the substitution position of the B(Mes) 2 moiety on the organic ligand, some electronic features, such as the electron injection/ electron transporting (EI/ET) properties and charge transport balance, can also be conferred to the phosphorescent Ir III complexes to give excellent electroluminescent (EL) characteristics. Highly efficient red phosphorescent bis(5-(dimesitylboryl)-2-phenylpyridinato)iridium(acetylacetonate) (Ir-B-1) based on the above notion shows a very good compatibility with the choice of host materials which can furnish maximum current efficiency (h L ) of 22.2 cd A À1 , external quantum efficiency (h ext ) of 14.7% and power efficiency (h P ) of 21.4 lm W À1 for the devices constructed with the conventional host materials. So, these exciting results will not only provide both the systematic guidelines for the phosphorescent color variation on the Ir III complexes with B(Mes) 2 units as well as a deeper insight into the conventional color-tuning approach on ppy-type Ir III complexes, but also offer a simple outlet to afford unique electronic features to these phosphorescent emitters to show admirable EL performance.
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