Bifunctional graphene oxide–cellulose nanofibril aerogel loaded with Fe(<scp>iii</scp>) for the removal of cationic dye via simultaneous adsorption and Fenton oxidation

Sajab, Mohd Shaiful; Chia, Chin Hua; Chan, Chi Hoong; Zakaria, Sarani; Kaco, Hatika; Chook, Soon Wei; Chin, Siew Xian; Noor, An’amt Mohamed

doi:10.1039/c5ra26193g

Cited by 79 publications

(55 citation statements)

References 39 publications

(48 reference statements)

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“…31 Therefore, as reported earlier, pH 7 was selected as the optimum medium. 7 The mechanism of adsorption on the surface of the adsorbent beads was investigated using several kinetic models. Pseudo-first-order, pseudo-second-order and intraparticle diffusion equations were used to find the best-fitted model.…”

Section: Results and Discussion Characterization Of The Prepared Cellmentioning

confidence: 99%

“…The adsorption performance, regeneration ability and adsorbent separation are other important features of an effective adsorbent. 7 Much research has been carried out on the use of biodegradable polymers with high adsorption capacities. The use of highly abundant low-cost renewable bioresources allows the development of products with a low impact on the environment.…”

Section: Introductionmentioning

confidence: 99%

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FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

Moosavi

Gan

Zakaria³

2019

Cellulose Chem. Technol.

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Modified regenerated cellulose beads functionalized with activated carbon (AC), as well as magnetic cellulose beads of AC-Fe 3 O 4 and AC-CoFe 2 O 4 , were synthesized. The AC was further used as adsorbent for the removal of cationic methylene blue (MB) dye from aqueous solution. The magnetic cellulose beads possessed a high magnetic response to an external magnetic field and their ease of recovery could be facilitated with the aid of a magnetic field. The synthesized adsorbents were characterized using a Field Emission Scanning Electron Microscope (FESEM), as well as by energy dispersive X-ray (EDX) spectrometry and thermogravimetric analysis (TGA). In comparison with the synthesized magnetic cellulose beads, the maximum adsorption capacity of the adsorbent beads assisted with AC, AC-Fe 3 O 4 and AC-CoFe 2 O 4 was of 54, 53 and 50 mg/g, respectively. The kinetic study of the adsorption of MB dye onto the adsorbents was performed at different parameters (initial dye concentration and temperature). The kinetics of the adsorption fit well with the pseudo-second-order model.

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Section: Results and Discussion Characterization Of The Prepared Cellmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

Moosavi

Gan

Zakaria³

2019

Cellulose Chem. Technol.

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“…8). Compared with other adsorbents presented in the literature 13,15,18,19,22,23,26 (as shown in Table S3 †), g-Fe 2 O 3 /C presented satisfactory adsorption capacity and degradation efficiency in this work, which can be considered as an alternative for the removal of reactive dyes from aqueous effluents.…”

mentioning

confidence: 85%

“…22 Moreover, the Fenton process has also successfully been used in the preparation of porous magnetic carbon materials. 23 Therefore, the discovery a rapid and simple method to prepare biomass-based activated carbon materials, which have both good adsorption and degradation performance, has great application value.…”

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confidence: 99%

Facile synthesis of low-cost biomass-based γ-Fe₂O₃/C for efficient adsorption and catalytic degradation of methylene blue in aqueous solution

et al. 2017

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In this study, a novel and low-cost method was developed for synthesizing magnetic porous g-Fe 2 O 3 /C as an adsorbent and catalyst for removal of methylene blue (MB) from aqueous solution. Using FeCl 3 $6H 2 O and bagasse as the precursor, the biomass-based material was synthesized rapidly using a microwave heating process. Fe ions were introduced to achieve both adsorption and catalytic degradation by the

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“…Further, Sajab and coworkers loaded graphene oxide–cellulose nanofibril aerogels with Fe(III) ions. The removal is based on Fenton oxidation mechanism, which in the presence of hydrogen peroxide lead to the degradation of methylene blue and achieved a significantly higher efficiency of 30.4% than unloaded fibers . Liu and coworkers enhanced the capacity of hydrogels by (15–23%) deacetylation of chitin nanofibers.…”

Section: Removal Of Dyesmentioning

confidence: 99%

Bio‐Based Nanofibers Involved in Wastewater Treatment

Gandavadi

Sundarrajan

Ramakrishna

2019

Macro Materials & Eng

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Studies involving bio‐based nanofibers are well utilized in the field of energy, catalysis, electronics, and environmental science. In this review, the importance of utilizing bio‐based materials for the development and optimization of multiplexed nanofibers and the modifications adopted to overcome the drawbacks of conventional electro‐spinning to facilitate better production rates, enhanced adsorption, and its potential in removing heavy metal ions, dyes, and other contaminants polluting the environment are highlighted. This work provides the readers the ability to understand the complexity in fabrication of bio‐based nanofibers focusing primarily on chitosan, cellulose, and protein‐based nanofibers and their mechanism toward quenching/degradation of water contaminants. In addition, it also provides the advantages of using bio‐based materials over synthetic materials for the development of nanofibers.

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Bifunctional graphene oxide–cellulose nanofibril aerogel loaded with Fe(iii) for the removal of cationic dye via simultaneous adsorption and Fenton oxidation

Abstract: A highly porous cellulose nanofibril aerogel loaded with graphene oxide–iron(iii) nanocomposites was produced and used for the treatment of methylene blue in aqueous solution.

Cited by 79 publications

References 39 publications

FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

Facile synthesis of low-cost biomass-based γ-Fe₂O₃/C for efficient adsorption and catalytic degradation of methylene blue in aqueous solution

Bio‐Based Nanofibers Involved in Wastewater Treatment

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Bifunctional graphene oxide–cellulose nanofibril aerogel loaded with Fe(iii) for the removal of cationic dye via simultaneous adsorption and Fenton oxidation

Abstract: A highly porous cellulose nanofibril aerogel loaded with graphene oxide–iron(iii) nanocomposites was produced and used for the treatment of methylene blue in aqueous solution.

Cited by 79 publications

References 39 publications

FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

FUNCTIONALIZED CELLULOSE BEADS WITH ACTIVATED CARBON Fe3O4/CoFe2O4 FOR CATIONIC DYE REMOVAL

Facile synthesis of low-cost biomass-based γ-Fe2O3/C for efficient adsorption and catalytic degradation of methylene blue in aqueous solution

Bio‐Based Nanofibers Involved in Wastewater Treatment

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Product

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Facile synthesis of low-cost biomass-based γ-Fe₂O₃/C for efficient adsorption and catalytic degradation of methylene blue in aqueous solution