Abstract:The oximes of some Mannich bases have been rearranged with phosphorus pentachloride in benzene, to yield p-aminopropionanilides. These p-arnino-derivatives, as their methiodides, react easily with aqueous base to yield substituted acrylanilides which can themselves be unambiguously synthesised from acryloyl chloride and the appropriate arylamine. The addition of dimethylamine to the substituted acrylanilides to yield the corresponding substituted p-aminopropionanilides was also achieved. The oximes of aryl vin… Show more
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.