1953
DOI: 10.1021/ac60077a023
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Barium Thiosulfate Monohydrate, Standard for Thiosulfate Iodometry

Abstract: Based upon a thesis to be submitted by P. B. Sweetser in partial fulfillment of the requirements for the degree 'of doctor of philosophy at Princeton University.

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Cited by 7 publications
(3 citation statements)
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“…Barium thiosulfate monohydrate, which may be obtained commercially from several sources, has a high equivalent weight (267.51 amu) and can be dried to constant weight without special procedure at 40 °C. Above about 50 °C, the hydrate slowly loses water, and the effects of high drying temperatures have been reported previously (4). The solubility of the salt, 0.283 gram of BaS20s per 100 cm3 of saturated solution at 25 °C (5), is insufficient to allow preparation of a O.IN solution.…”
mentioning
confidence: 80%
“…Barium thiosulfate monohydrate, which may be obtained commercially from several sources, has a high equivalent weight (267.51 amu) and can be dried to constant weight without special procedure at 40 °C. Above about 50 °C, the hydrate slowly loses water, and the effects of high drying temperatures have been reported previously (4). The solubility of the salt, 0.283 gram of BaS20s per 100 cm3 of saturated solution at 25 °C (5), is insufficient to allow preparation of a O.IN solution.…”
mentioning
confidence: 80%
“…1 mL of bacteria culture was taken every 4 h and centrifuged at 13,000 rcf for 3 min and retained the supernatant for analysis. The indirect iodometry 41 was used to determine the tetrathionate metabolism.…”
Section: Determination Of Tetrathionate Metabolism Inmentioning
confidence: 99%
“…The barium salt seems a poor alternative since it is too insoluble to prepare 0.1 M solutions, besides requiring large amounts of material in its preparation (4). We have now found that the crystalline pentahydrate, or even concentrated aqueous solutions, can be dehydrated with hot methanol in a matter of minutes to a loose powder of the anhydrous form.…”
Section: Literature Citedmentioning
confidence: 99%