Bomb calorim e tri c meas ure ments a re reported for the co mbu stio n in flu orine of polytetrafluoro· e t.hyle ne (T eflon) and graphite·polyte traflu oroethyle ne mixtures. Mass s pectrometri c ex amination of the produ ct gases show ed C F" to be the only maj or produc t with C" F6(g) prese nt in only very s mall a mount s . Th e co mpl e te ness of co mbu sti on of th e graphit e wa s de termin ed by c he mi cal analysis of co mbu stion res idu es and found to ra nge from 97 to be tte r than 99 perce nt. Fro m th e co mbu stion data, th e hea ts of form ati on ~H;l>I8 [ CF4(g)] and ~H;,,,~[ C"F4 (solid polym e r)] we re de te rmined to be -222.87 ± 0.38 kcal mol -I and -197.82 ± 0.39 kcal (gfw C2F.) -I , respectively. Th e un certainties are estimates of the ove raU experimental e rrors .A previously re port.ed value for the heat of formati on of AlF3(c) is adju sted to be co ns iste nt. with t.h e presen t work. An e valu ation of oth er data on CF 4 is prese nted. Th e heat of formation of CF.(g) is co mbined with other wo rk to de rive the heats of formation of HF soluti ons a t three s pecific con· ce ntrati ons.Key Words : Alum inum fluorid e, c arbon te trafluorid e . flu orine, fluorin e bomb calorim e try, graph ite , heat of co mbusti on, heat of form a tion, hydroge n flu oride aqueous, T efl on.