Methane (CH 4 ) is thought to have played an important role as a greenhouse gas in warming the Archean Earth (Catling & Zahnle, 2020;Haqq-Misra et al., 2008). The Archean is the geological eon spanning 4.0-2.5 billion years ago (Ga). The Archean was believed to be oxygen poor, with oxygen concentrations less than 3 × 10 −6 of the present atmospheric level (PAL) (B. S. Gregory et al., 2021), which allowed reduced gases, such as methane, to accumulate in the atmosphere (Catling et al., 2001). Here, we look to understand the potential role of methane, and to a lesser extent carbon dioxide (CO 2 ), on the Archean climate using a three-dimensional general circulation model (GCM), at various carbon dioxide concentrations. The use of a GCM further allows an understanding to be gained of the effect of methane on the global mean climate and the meridional temperature structure.The Archean could have supported high methane concentrations at various points in its history (e.g., Figure 5 in Catling & Zahnle, 2020). A primitive pre-photosynthetic biosphere would effectively turn reductant (electron donors) from mantle inputs or oxidation of the crust into reduced organic carbon and ultimately methane (e.g., Nicholson et al., 2022). As methane will be photolyzed to hydrogen at high altitude, atmospheric methane levels are then determined by the balance between surface net reductant (hence methane) input, and hydrogen escape (Claire et al., 2006;Goldblatt et al., 2006;Kharecha et al., 2005). Kharecha et al. ( 2005) used a coupled ecosystem-atmosphere model to suggest that the early Archean biosphere could have sustained methane concentrations between 100 and 35,000 ppm (equivalent to 10-3,500 Pa in surface partial pressure for a 10 5 Pa atmosphere). Subsequent evolution of increasingly productive photosynthetic biospheres and ultimately oxygenic photosynthesis could increase methane concentrations as they increase the net reductant input via oxidation of crustal material (primarily Fe, Walker, 1987). This is supported by a depletion in organic carbon-13 in deep Abstract Methane is thought to have been an important greenhouse gas during the Archean, although its potential warming has been found to be limited at high concentrations due to its high shortwave absorption. We use the Met Office Unified Model, a general circulation model, to further explore the climatic effect of different Archean methane concentrations. Surface warming peaks at a pressure ratio pCH 4 :pCO 2 of approximately 0.1, reaching a maximum of up to 7 K before significant cooling above this ratio. Equator-to-pole temperature differences also tend to increase up to pCH 4 ≤ 300 Pa, which is driven by a difference in radiative forcing at the equator and poles by methane and a reduction in the latitudinal extend of the Hadley circulation. 3D models are important to fully capture the cooling effect of methane, due to these impacts of the circulation.
Plain Language SummaryThe Archean is a period in Earth history spanning approximately 4 to 2.5 billion years ago. D...