Association in mixed alkali halide vapors

Guion, J.; Hengstenberg, D.; Blander, M.

doi:10.1021/j100859a044

Cited by 6 publications

(7 citation statements)

References 1 publication

(1 reference statement)

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“…The standard formation potentials for pure molten AgC1 have been measured previously in this laboratory (5) and are in good agreement with other electrochemical measurements (13)(14)(15) and thermochemical data (16). The ex-moo-.15oo-J4oo Cell: Ag KCI.CsCI.AgCI C,CI 2 .…”

Section: Resultssupporting

confidence: 87%

“…[8] and Eq. [13] are summarized in Table VIII with respect to a standard chlorine reference electrode. These also represent EMF series in various solvent melts.…”

Section: Discussionmentioning

confidence: 99%

“…[12] allows the calculation of E~ which is generally not directly measurable because of the extreme reactivity of MCI=+I solutions with metal M. The formal redox potential for the reaction of Eq. [13] can also be expressed as…”

mentioning

confidence: 99%

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Potential Measurements of Reactive Metal Chlorides in Alkali Halide Solutions: I . Silver, Cobalt, Nickel, Iron, and Copper

Tumidajski

Flengas

1990

J. Electrochem. Soc.

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The thermodynamic behavior of CoC12, NiC12, FeC12, CuC1, FeC13, and CuC12 was investigated in NaC1, KC1, CsC1, or the equimolar mixtures of these salts between 700~176 using galvanic or redox cells with a silver-silver chloride reference electrode. The results indicate solutions which are reactive and nonideal. ExperimentalThe metal chlorides and CsC1 were anhydrous and they were received in sealed ampuls packed under argon gas.

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Section: Resultssupporting

confidence: 87%

“…[8] and Eq. [13] are summarized in Table VIII with respect to a standard chlorine reference electrode. These also represent EMF series in various solvent melts.…”

Section: Discussionmentioning

confidence: 99%

See 1 more Smart Citation

Potential Measurements of Reactive Metal Chlorides in Alkali Halide Solutions: I . Silver, Cobalt, Nickel, Iron, and Copper

Tumidajski

Flengas

1990

J. Electrochem. Soc.

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“…These constants are given in Table XI. As has been pointed out (Guion et al, 1968), these associations cannot be described in terms of any simple pair potential, and a full understanding of these mixed species will require accurate quantum mechanical calculations or the development of accurate pair potentials. All values of K for reaction (55) are larger than 4 except for those in NaCl-CsCl mixtures.…”

Section: Discussionmentioning

confidence: 99%

The Thermodynamic Properties of Alkali Halide Vapors

Blander

1979

Alkali Halide Vapors

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“…Enthalpy of mixing information on the binary NaCl-CsCl is also available (34) and the electrochemical and the calorimetric data are in very good agreement. The ternary system AgCl-NaC1-CsC1 has been investigated by the emf method (21) and the comparison between experimental and calculated excess free energies of mixing is excellent.…”

Section: Agreement With Experimental Evidencementioning

confidence: 99%

Thermodynamic treatment of multicomponent fused salt solutions: common anion reactive systems approximation

Flengas¹

1991

Can. J. Chem.

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From a modified F.F.G. (1) thermodynamic cycle, equations have been developed from which the molar and partial molar excess thermodynamic properties of j-component molten salt solutions may be predicted from binary data.The theory is applicable to reactive molten salt systems and particularly to charge asymmetric fused salt solutions with common anions.It is shown that for a system having j + 1 components, such as [Formula: see text], any molar or partial molar property of mixing for MXq, may be calculated from available data on corresponding j-binary systems, such as MXq–AX, MXq–BX, and [Formula: see text].The equations are of the general form,[Formula: see text]The latter is applicable only when the multicomponent and the binary solutions have the same MXq content and same temperature.The theoretical expressions have been found to predict quite well available data on ternary and quarternary systems. New composition parameters for expressing the compositions in quarternary and quinary systems have been established. Key words: molten salt solutions, multicomponent systems, ternary systems, quarternary systems, quinary systems.

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Association in mixed alkali halide vapors

Cited by 6 publications

References 1 publication

Potential Measurements of Reactive Metal Chlorides in Alkali Halide Solutions: I . Silver, Cobalt, Nickel, Iron, and Copper

Potential Measurements of Reactive Metal Chlorides in Alkali Halide Solutions: I . Silver, Cobalt, Nickel, Iron, and Copper

The Thermodynamic Properties of Alkali Halide Vapors

Thermodynamic treatment of multicomponent fused salt solutions: common anion reactive systems approximation

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