Association and charge transfer reactions of Xe+ and O2+ with acetonitrile

Vinogradov, P. S.; Borisenko, D.M.; Hansel, Armin; Taucher, J.; Ferguson, E. E.; Lindinger, W.

doi:10.1016/j.ijms.2004.12.021

Cited by 4 publications

(1 citation statement)

References 11 publications

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“…Comparison of F 2 N À Xe + with other Xe À N cations: The only xenon-nitrogen cations observed so far in the gas phase are the simplest, XeN + and XeN 2 + . [54,55] Other molecular species such as XeF + (N 2 O) [56] and Xe + (CH 3 CN) [57] have been as well reported, but their connectivities are still not ascertained. F 2 NÀXe + is indeed the first gaseous congener of the xenon-nitrenium cations (FO 2 S) 2 NXe + , [19,25] F 5 SN(H)Xe + , [33] and F 5 TeN(H)Xe + [30] observed in the condensed phase as AsF 6 À or Sb 3 F 16 À salts.…”

Section: Speciesmentioning

confidence: 99%

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺

Operti

Ragazzoni

Turco

et al. 2011

Chemistry A European J

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The xenon-difluoronitrenium ion F(2)N-Xe(+) , a novel xenon-nitrogen species, was obtained in the gas phase by the nucleophilic displacement of HF from protonated NF(3) by Xe. According to Møller-Plesset (MP2) and CCSD(T) theoretical calculations, the enthalpy and Gibbs energy changes (ΔH and ΔG) of this process are predicted to be -3 kcal mol(-1) . The conceivable alternative formation of the inserted isomers FN-XeF(+) is instead endothermic by approximately 40-60 kcal mol(-1) and is not attainable under the employed ion-trap mass spectrometric conditions. F(2)N-Xe(+) is theoretically characterized as a weak electrostatic complex between NF(2)(+) and Xe, with a Xe-N bond length of 2.4-2.5 Å, and a dissociation enthalpy and free energy into its constituting fragments of 15 and 8 kcal mol(-1), respectively. F(2)N-Xe(+) is more fragile than the xenon-nitrenium ions (FO(2)S)(2)NXe(+), F(5)SN(H)Xe(+), and F(5)TeN(H)Xe(+) observed in the condensed phase, but it is still stable enough to be observed in the gas phase. Other otherwise elusive xenon-nitrogen species could be obtained under these experimental conditions.

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Section: Speciesmentioning

confidence: 99%

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺

Operti

Ragazzoni

Turco

et al. 2011

Chemistry A European J

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Peroxynitrogen: A Study of Nitrogen/Oxygen Heterocycles with N  O and O  O or N  O  O Bonding

Slayden

Greer

Liebman

2010

Patai's Chemistry of Functional Groups

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Current literature in mass spectrometry

2006

J. Mass Spectrom.

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In order to keep subscribers up‐to‐date with the latest developments in their field, John Wiley & Sons are providing a current awareness service in each issue of the journal. The bibliography contains newly published material in the field of mass spectrometry. Each bibliography is divided into 11 sections: 1 Books, Reviews & Symposia; 2 Instrumental Techniques & Methods; 3 Gas Phase Ion Chemistry; 4 Biology/Biochemistry: Amino Acids, Peptides & Proteins; Carbohydrates; Lipids; Nucleic Acids; 5 Pharmacology/Toxicology; 6 Natural Products; 7 Analysis of Organic Compounds; 8 Analysis of Inorganics/Organometallics; 9 Surface Analysis; 10 Environmental Analysis; 11 Elemental Analysis. Within each section, articles are listed in alphabetical order with respect to author (4 Weeks journals ‐ Search completed at 28th. Dec. 2005)

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Association and charge transfer reactions of Xe+ and O2+ with acetonitrile

Cited by 4 publications

References 11 publications

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺

Peroxynitrogen: A Study of Nitrogen/Oxygen Heterocycles with N  O and O  O or N  O  O Bonding

Current literature in mass spectrometry

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Association and charge transfer reactions of Xe+ and O2+ with acetonitrile

Cited by 4 publications

References 11 publications

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F2NXe+

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F2NXe+

Peroxynitrogen: A Study of Nitrogen/Oxygen Heterocycles with N  O and O  O or N  O  O Bonding

Current literature in mass spectrometry

Contact Info

Product

Resources

About

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F₂NXe⁺