Pesticides and fertilizers use in parts of Rivers Niger and Kaduna catchments, north central, Nigeria was investigated. Contamination of the rivers and their resources due to unsustainable use of pesticides and fertilizers by local farmers are a major problem in the study area. Also, data from the study of pesticides and fertilizer use remain scanty and therefore needed. The objective is to find the opportunity for all stakeholders to improve on the overall environmental performance. Extensive field survey was conducted using various participatory appraisals techniques involving key stakeholders in the area. Collated data were analysed using descriptive statistical methods (frequency percentage). The results of findings identify unsustainable use of fertilizers and pesticides by farmers in the study area. It further shows respondents in the study area applied high rate of fertilizers and pesticides during farming activities which obviously improved crop yield but in turn lead to water quality degradation. Virtually, majority of the farmers have little or no measures towards ensuring protection of water and biota from the potential danger of pesticides and fertilizers use in the study area. These attitudes discovered could lead to water quality degradation, biodiversity disruption and subsequent negative impact on economic development in the study area. In view of the above, it is recommended that visible and effective environmental management policies in respect of agrochemicals use in the study area be put in place to guarantee cleaner and healthier environment for all.