As12tBu8 – ein Tricyclo[6.4.0.02,6]dodecaarsan

Baudler, M.; Wietfeldt‐Haltenhoff, Stefan

doi:10.1002/ange.19850971126

Angew. Chem.

1985

DOI: 10.1002/ange.19850971126

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As12tBu8 – ein Tricyclo[6.4.0.02,6]dodecaarsan

M. Baudler

Stefan Wietfeldt‐Haltenhoff

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1985

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Cited by 7 publications

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“…As6fBu4, [61 As,6tBu,0,(61 (As~Bu),,'~] and (AstBu)51s1 are formed together with small amounts of further tert-butylarsanes containing up to 20 arsenic atoms in the molecule. [61 The product pattern is strongly dependent on the reaction conditions (molar ratio and concentration of the reactants, reaction rate, duration of additional stirring).…”

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As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane

Baudler

Wietfeldt‐Haltenhoff

1985

Angew. Chem. Int. Ed. Engl.

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confidence: 99%

As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane

Baudler

Wietfeldt‐Haltenhoff

1985

Angew. Chem. Int. Ed. Engl.

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Polyphosphorverbindungen – neue Ergebnisse und Perspektiven

Baudler

1987

Angewandte Chemie

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151

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Professor Heinz Harnisch zum 60. Geburtstag gewidrnetPolyphosphorverbindungen haben -im Gegensatz zu den zahlreichen bekannten und auch technisch wichtigen Mono-und Diphosphorverbindungen der maximalen Oxidationsstufe dieses Elementes -bis vor zwei Jahrzehnten ein Schattendasein gefiihrt. Ein Grund dafur waren die Eigenschaften dieser Verbindungen, die ihre Handhabung und strukturelle Charakterisierung erschwerten. Durch die Entwicklung moderner praparativer Arbeitstechniken und vor allem durch die methodische Weiterentwicklung der Kernresonanzspektroskopie lieBen sich diese Probleme losen, so daD in letzter Zeit ein faszinierendes neues Teilgebiet der Phosphorchemie erschlossen werden konnte, iiber das erstmals vor fiinf Jahren zusammenfassend berichtet worden ist. Seitdem hat der Ausbau dieser ,,Element-nahen" Chemie des Phosphors weiterhin beeindruckende Fortschritte gemacht ; heute ist eine erstaunliche Vielfalt von Verbindungen mit einem Geriist aus Phosphorketten oder -ringen bekannt. DaB dieses Gebiet aber noch immer gut ftir Uberraschungen ist, zeigt die jiingst beim Aufbau von P-reicheren aus P-armeren Polyphosphiden in Lbsung beobachtete spontane Bildung des ,,aromatischen" Pentaphosphacyclopentadienid-Ions, P 7 , ebenso wie die Entdeckung der Inversion des Phosphors bei tetra-und pentacyclischen Organophosphanen.

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Polyphosphorus Compounds—New Results and Perspectives

Baudler

1987

Angew. Chem. Int. Ed. Engl.

221

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Dedicated to Professor Heinz Harnisch on the occasion of his 60th birthdayIn contrast to the numerous known and often technically important mono-and diphosphorus compounds with phosphorus in its maximum oxidation state, polyphosphorus compounds led only a shadowy existence up to about twenty years ago. One of the reasons for this was the properties of such compounds, which made their handling and structural characterization difficult. This problem was solved by the development of modern preparative techniques and, especially, by the further methodological development of nuclear magnetic resonance spectroscopy. Thus, a fascinating new branch of phosphorus chemistry has been opened up in recent years. The first comprehensive review on this subject was published five years ago. Since then, research on this "element-near'' chemistry of phosphorus has produced further impressive advances with the result that a surprisingly large variety of compounds with skeletons consisting of chains or rings of phosphorus atoms is known today. However, the recent observation of the spontaneous formation of the "aromatic" pentaphosphacyclopentadienide ion, P ;, during the synthesis of phosphorus-richer polyphosphides from phosphorus-poorer compounds in solution and the discovery of the inversion of phosphorus in tetra-and pentacyclic organophosphanes demonstrate that this field is still capable of producing surprises.

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As12tBu8 – ein Tricyclo[6.4.0.02,6]dodecaarsan

Cited by 7 publications

References 14 publications

As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane

As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane

Polyphosphorverbindungen – neue Ergebnisse und Perspektiven

Polyphosphorus Compounds—New Results and Perspectives

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Product

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About

As12tBu8 – ein Tricyclo[6.4.0.02,6]dodecaarsan

Cited by 7 publications

References 14 publications

As12tBu8—a Tricyclo[6.4.0.02,6]dodecaarsane

As12tBu8—a Tricyclo[6.4.0.02,6]dodecaarsane

Polyphosphorverbindungen – neue Ergebnisse und Perspektiven

Polyphosphorus Compounds—New Results and Perspectives

Contact Info

Product

Resources

About

As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane

As₁₂tBu₈—a Tricyclo[6.4.0.0^2,6]dodecaarsane