“…Hence, advective transport in open macropores and major fractures happens relatively fast compared to transport in the clayey till matrix where diffusion is the dominant transport process (Jin et al., 2014; Koestel & Larsbo, 2014; Muniruzzaman & Rolle, 2019; Parker et al., 2008; Rolle et al., 2013) However, the appearance of large‐aperture fractures (few tens to a few hundred micrometers) and macropores (e.g., earthworm burrows, root channels) is often limited to the few uppermost meters of the soils. The fracture density often decreases below that (Harrar et al., 2007; Jørgensen, McKay, et al., 2004; Mckay & Fredericia, 1995) and smaller apertures can be observed (Helmke et al., 2005a; Young et al., 2019), with few to no macropores. For long residence times, matrix diffusion can considerably slow down contaminant transport through fractures due to a continuous transfer of the solute from the fractures to the matrix (e.g., Carrera et al., 1998; Grisak & Pickens, 1980; Lipson et al., 2005; Mosthaf et al., 2018), with the solute flux into the matrix that may be enhanced by sorption to solid phase organic carbon (e.g., Parker et al., 1994).…”