Applications recentes de la reaction de retro-diels-alder en synthese organique

Ripoll, Jean‐Louis; Rouessac, Annick; Rouessac, F.

doi:10.1016/0040-4020(78)88032-6

Cited by 119 publications

(21 citation statements)

References 160 publications

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“…12), whereas a 2-substituted diene gives mainly "para" substitution (Eq. 13) (16). "Meta"-like products 13 (14) and 14 are either absent or, at best, minor products.…”

Section: Regioselectivitymentioning

confidence: 99%

Selectivity: A Key to Synthetic Efficiency

Trost

1983

Science

306

231

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The efficient synthesis of organic compounds requires the development of processes with enhanced selectivity. Selectivity is categorized according to chemical reactivity (chemoselectivity), orientation (regioselectivity), and spatial arrangement (diastereoselectivity and enantioselectivity). Recent developments in reduction-oxidation methods and C-C bond forming reactions illustrate some solutions to problems of selectivity. The design of selectivity-inducing groups and the increased role of main group and transition metals in enhancing selectivity are especially noted.

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“…12), whereas a 2-substituted diene gives mainly "para" substitution (Eq. 13) (16). "Meta"-like products 13 (14) and 14 are either absent or, at best, minor products.…”

Section: Regioselectivitymentioning

confidence: 99%

Selectivity: A Key to Synthetic Efficiency

Trost

1983

Science

306

231

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“…Indeed, maleimide double bond is known to be reactive at high temperature [25] especially in the presence of epoxy function as shown by Ashok Kumar et al [26]. As many authors quoted in organic synthesis [27][28][29], the protection of dienophile maleimide double bond can be accomplished through a Diels-Alder reaction using furan as diene. Fig.…”

Section: Synthesis Of Fac32/amu Adduct and Its Diels-alder And Retro-mentioning

confidence: 96%

Thermally reversible crosslinked polyethylene using Diels–Alder reaction in molten state

Magana

Zerroukhi

Jegat

et al. 2010

Reactive and Functional Polymers

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“…This was attempted by the flash vacuum thermolysis (FVT) [9,101 of 3g in the hope of losing the ethylene bridge with simultaneous elimination of ClTms and the formation of the corresponding phosphinine. This type of reaction was not ob- served.…”

Section: Attempts To Aromatize 3gmentioning

confidence: 99%

Synthesis of functionalized phosphinines: Aromatization of Diels‐Alder adducts of P‐chlorobis(trimethylsilyl)methylenephosphine

Abbari

Carriéa

1991

Heteroatom Chemistry

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The Diels‐Alder adducts of functionalized dienes with P‐chloro‐bis(trimethylsilyl)methylenephosphine can be aromatized, except in a few particular cases, thus opening a general route to functionalized phosphinines. The aromatization procedure differs with the substituents. Intermediates such as secondary cyclic phosphines could be characterized and even isolated. In some cases, aromatization and 1,5 sigmatropic shift of a trimethylsilyl group were observed and hydrogenolysis of the CSi bond as well.

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Applications recentes de la reaction de retro-diels-alder en synthese organique

Cited by 119 publications

References 160 publications

Selectivity: A Key to Synthetic Efficiency

Selectivity: A Key to Synthetic Efficiency

Thermally reversible crosslinked polyethylene using Diels–Alder reaction in molten state

Synthesis of functionalized phosphinines: Aromatization of Diels‐Alder adducts of P‐chlorobis(trimethylsilyl)methylenephosphine

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