Organic compounds containing a variety of functional
groups have
been analyzed using aerosol time-of-flight
mass spectrometry. Both
positive and negative laser
desorption/ionization mass spectra have
been acquired
for compounds of relevance to ambient air
particulate
matter, including polycyclic aromatic hydrocarbons,
heterocyclic analogues, aromatic oxygenated compounds
such as
phenols and acids, aliphatic dicarboxylic acids,
and reduced
nitrogen species such as amines. In many
cases, positive ion mass
spectra are similar to those found
in libraries for 70-eV electron
impact mass spectrometry.
However, formation of even-electron
molecular ions due
to adduct formation also plays a major role in
ion formation. Negative ion mass spectra suggest that organic
compounds largely disintegrate into carbon cluster fragments (C
n
-
and C
n
H
-
). However, information about the
heteroatoms present in
organic molecules, especially
nitrogen and oxygen, is carried
dominantly by negative
ion spectra, emphasizing the importance
of simultaneous
analysis of positive and negative ions in
atmospheric
samples.