Application of Organic Amine Modified Natural Zeolite in Filling Natural Rubber

Abstract

In this paper, the method of filling natural rubber with zeolite as filler was mainly studied in the following two aspects: firstly, experiments selected organic amine surface modifier to modify natural zeolite and used infrared spectroscopy to analyze the interaction between the modifier and zeolite, and secondly, studying the application of modified zeolite in natural rubber and using scanning electron microscopy to analyze the mechanism of action between zeolite and natural rubber. The test results show that octadecylamine in the modifier had the relatively best effect. Under the best conditions, the activation index of the modified product could reach 95% and above, and the contact angle could reach about 100°. When the filling amount was 30 phr, the octadecylamine modification had the most obvious effect on the performance of zeolite/natural rubber and the composite rubber had better mechanical properties. The corresponding tensile strength, tear strength, elongation at break and Shore hardness were 22.59 MPa, 28.52 MPa, 782.1% and 41, respectively, which were 45.74%, 19.28%, 7.95% and 7.89% higher than those of unmodified zeolite/natural rubber. As the first study of organic amine modified zeolite as a filler for filling natural rubber, this work provides a new way to improve the added value of natural zeolite.