Abstract:A six sensor electrode system was developed to distinguish three tea extract samples by using impedance measurement technology. Five of the six sensing electrodes were made of different wt% single walled carbon nanotubes (SWCNT) and electropolymerizedpyrrole over the surface of gold electrodes. The sixth electrode was made by electropolymerizedpyrrole doped with Poly (sodium-4-styrenesulfonate). The sensing electrodes were characterized by FT-IR, Cyclic Voltammetry, and Transmission Electron Microscope. Variou… Show more
“…In fact, because the electrical impedance allows the quantification of the behaviour of a conducting medium to an electric current, the impedance measurement is used in the determination of the electromagnetic properties of materials and is the basis of various methods of electrical transduction with applications in fields such as chemistry [22,23] and biomedicine [24][25][26][27]. Electrical impedance measurement is important not only in the analysis of electric circuits but also for other purposes.…”
“…In fact, because the electrical impedance allows the quantification of the behaviour of a conducting medium to an electric current, the impedance measurement is used in the determination of the electromagnetic properties of materials and is the basis of various methods of electrical transduction with applications in fields such as chemistry [22,23] and biomedicine [24][25][26][27]. Electrical impedance measurement is important not only in the analysis of electric circuits but also for other purposes.…”
Polyaniline (PANI) is doped with H2SO4, HCl, poly(acrylic acid) (PAA), poly(acrylic acid‐co‐maleic acid) (PAMA), PAA+HCl, and poly(styrenesulfonic acid) (PSS) to obtain PANI‐H2SO4, PANI‐HCl, PANI‐PAA, PANI‐PAMA, PANI‐(PAA+HCl), and PANI‐PSS films, respectively. Ultraviolet‐visible (UV‐Vis) and Fourier transform infrared (FT‐IR) spectroscopy result confirm that PANI is doped with PSS. X‐ray photoelectron spectroscopy (XPS) results indicate that the nitrogen atoms of PANI‐PSS are the most positively charged in these films. Scanning electron microscopy (SEM) images reveal that these films are composed of highly porous nanowires. Platinum (Pt) can be incorporated into PANI‐H2SO4, PANI‐HCl, PANI‐PAA, PANI‐PAMA, PANI‐(PAA+HCl), and PANI‐PSS films via electrochemical deposition to obtain PANI‐H2SO4‐Pt, PANI‐HCl‐Pt, PANI‐PAA‐Pt, PANI‐PAMA‐Pt, PANI‐(PAA+HCl)‐Pt, and PANI‐PSS‐Pt composite electrodes, respectively. Auger electron spectroscopy (AES) results indicate that Pt particles disperse more uniformly into the spatial regions of PANI‐PSS and PANI‐(PAA+HCl) than those of other films. The PANI‐PSS‐Pt electrode provides the most active surface area of Pt in these electrodes. Cyclic voltammetry results and chronoamperometric response measurements show that the activity and stability toward methanol oxidation of the PANI‐PSS‐Pt electrode are the best in these electrodes.
The fabrication, characterization, and application of a nanostructured zinc oxide/ graphene (ZnO/Gr) transducer were described for the determination of urea concentration. For this purpose, thin films of sol-gel-synthesized ZnO nanostructure and Gr were prepared using the spin coating technique on the conductive fluorinated-tin oxide (FTO) substrate. Appropriate correlations between the spinning parameters and thin film features were established so that an efficient ZnO-Gr thin film was obtained. Field emission scanning electron microscopy (FE-SEM) images prove thin film pores to be an operative biosensing zone for urease (Urs) enzyme immobilization.Step-by-step monitoring of FTO/ZnO-Gr/Urs biosensor fabrication was achieved using electrochemical methods. The impedimetric results of a fabricated FTO/ZnO-Gr/Urs biosensor show high sensitivity for urea detection within 5.0-125.0 mg/dL and a limit of detection of 3.36 mg/dL.
K E Y W O R D Simpedimetric assessment, sol gel, spin coating, urea biosensor, ZnO-graphene
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