The formation of highly activated ultrashallow junctions is one of the main challenges for the forthcoming generation of complementary metal oxide semiconductor (CMOS) devices. Co-implantation of impurities such as carbon (C) or fluorine (F) is an attractive technique. However, junction optimization can only be achieved with a complete understanding of the underlying physical mechanisms. In this paper, the effect of
C∕F
co-implant on boron (B)-doped preamorphized silicon during the soak annealing is extensively studied.
C∕F
atoms are located in the middle range between the
B∕BF2
concentration profiles and the end-of-range (EOR) defect band, with the aim of reducing the interactions of dopants with the interstitials released from EOR region. Isochronal annealing study is performed to investigate the impact of
C∕F
codoping on the dopant de/reactivation behavior. It is shown that transient enhanced diffusion can be reduced by both co-implant schemes. The B-doped junction formed with the C co-implant is relatively stable and dopant deactivation is inhibited, while it is presumed that F atoms form
B–F
complexes, which reduces the B activation level. A physical insight on the dopant-defect interactions associated with
C∕F
co-implant is established through the combination of diffusion and activation studies during soak annealing.