2012
DOI: 10.1007/s11043-012-9195-8
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Applicability condition of time–temperature superposition principle (TTSP) to a multi-phase system

Abstract: The applicability condition of the time-temperature superposition principle (TTSP) to a multi-phase system is analytically discussed assuming a mixture law. It was concluded that the TTSP does not hold for a multi-phase system in general but does hold for a multi-component system in which some components have the same temperature dependence and the others have no temperature dependence. On the basis of the results, the application of the TTSP to plant materials such as wood and bamboo was examined using a mixt… Show more

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Cited by 28 publications
(21 citation statements)
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References 35 publications
(38 reference statements)
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“…At a reference temperature of 20 • C the CFRP is far below its glass transition, hence the damping is mostly affected by the elastomer. In addition, Nakano's suggestion [22], that in a multi-phase system only one material may show a temperature dependence for the applicability of the TTS can be considered valid in this temperature range. If one compares the curves of the temperature sweeps of the C-A-C and the A-C-A lay-ups in Figures 5 and 7, an increase in the loss factor can only be seen at a temperature of over 80 • C. Hence, Figure 10a is regarded as valid in the frequency range shown.…”
Section: Influence Of Frequencymentioning
confidence: 99%
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“…At a reference temperature of 20 • C the CFRP is far below its glass transition, hence the damping is mostly affected by the elastomer. In addition, Nakano's suggestion [22], that in a multi-phase system only one material may show a temperature dependence for the applicability of the TTS can be considered valid in this temperature range. If one compares the curves of the temperature sweeps of the C-A-C and the A-C-A lay-ups in Figures 5 and 7, an increase in the loss factor can only be seen at a temperature of over 80 • C. Hence, Figure 10a is regarded as valid in the frequency range shown.…”
Section: Influence Of Frequencymentioning
confidence: 99%
“…For these lay-ups the loss factor peak in T g CFRP range is always higher than for the specimens without elastomer (see Figures 5 and 7). However, the dominance of one relaxation mechanism is required for the applicability of the time-temperature superposition by horizontal shifts [21,22]. This might lead to the different locations of the loss factor peaks of the CFRP in the master curves in Figures 9 and 10b as the elastomer might also influence the behavior.…”
Section: Influence Of Frequencymentioning
confidence: 99%
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“…TTSP is effective for analyzing the in situ softening of lignin and for improving the understanding of structure/property relationships in plasticized lignocellulose (Salmén 1984;Laborie et al 2004;Chowdhury and Frazier 2013). However, the applicability of TTSP to wood is still controversial, and some researchers stated that it was applicable only under limited conditions (Salmén 1984;Kelley et al 1987;Nakano 1995Nakano , 2013. Salmén (1984) stated that the WLF model was applicable for water-saturated wood when the temperature was within T g to T g + 30°C.…”
Section: Introductionmentioning
confidence: 99%
“…At a higher temperature, shorter time, and lower temperature over a longer period of time, the same mechanical relaxation phenomenon can be observed, which is referred to as the time-temperature superposition principle (TTSP). The TTSP was originally used to analyze material viscoelasticity [25], and it is widely used to analyze the mechanical properties of wood [26], such as wood creep performance [27][28][29]. The TTSP was also used in thermal degradation analysis combined with the Arrhenius equation, and it has been used for the determination of the color change of cellulose [30] and wood-plastic composite discoloration analysis [31].…”
Section: Introductionmentioning
confidence: 99%