2013
DOI: 10.1209/0295-5075/102/39002
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Annular cracks in thin films of nanoparticle suspensions drying on a fiber

Abstract: We report an experimental study of the crack pattern formed during the drying of a colloidal suspension. A horizontal fiber, which provides a one dimensional, boundary-free substrate, is coated by a film of micronic thickness. The geometry imposes a remarkable annular crack pattern and allowing precise measurements of the crack spacing over a short range of film thickness (between 2 and 10 µm) which varies linearly with the film height. We compare our experimental data with a model proposed by Kitsunezaki whic… Show more

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Cited by 12 publications
(10 citation statements)
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“…The quantitative discrepancy may be explained by the elasticity of the substrate which increases the spacing [50] since it absorbes some elastic energy; But this elasticity is not taken into account in our solution contrary to theirs. Other papers [13,51,52] report a constant value of α independently of h, decreasing when the adhesion decreases, apparently in qualitative agreement with our model. It is however difficult to conclude since adhesion may play on both, debonding energy and bottom friction (which changes the boundary condition at the substrate hence the stress field and elastic energies).…”
Section: For σ B > σ Dsupporting
confidence: 91%
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“…The quantitative discrepancy may be explained by the elasticity of the substrate which increases the spacing [50] since it absorbes some elastic energy; But this elasticity is not taken into account in our solution contrary to theirs. Other papers [13,51,52] report a constant value of α independently of h, decreasing when the adhesion decreases, apparently in qualitative agreement with our model. It is however difficult to conclude since adhesion may play on both, debonding energy and bottom friction (which changes the boundary condition at the substrate hence the stress field and elastic energies).…”
Section: For σ B > σ Dsupporting
confidence: 91%
“…Finally, the present modelling framework is versatile, its extension to other geometries (e.g. multilayers [38], cylinder [52]), loading (e.g. uniaxial tension of the substrate [16]) and dissipation sources (e.g.…”
Section: For σ B > σ Dmentioning
confidence: 99%
“…To understand the general situation of a complex three-dimensional network of fibers [20], the wetting has been studied in different fiber configurations. When a liquid is coated on a single fiber [21,22,23], depending upon its rheological properties [24,25], the liquid can undergo a Rayleigh-Plateau instability, which results in a series of droplets [26]. A liquid droplet placed on a single fiber can adopt a barrel shape, a clam-shell shape or detach as gravitational forces dominate capillary forces [27,28,29].…”
Section: Introductionmentioning
confidence: 99%
“…Cracks and fractures are very common phenomena occurring in various contexts [1][2][3][4]. They are observed during the desiccation of films made of colloidal suspensions, like bentonite clay or cornstarch [5][6][7][8][9][10][11], in sol-gel films [12,13], in broken objects like windows [14][15][16] or in sea ice [17,18] and ice floes collisions [19,20].…”
Section: Introductionmentioning
confidence: 99%