“…Owing to the non-amenable character, PhOCH 3 and its related derivatives have been used as a universal green-solvent similar to ethanol and water for various chemical [19][20][21] and electrochemical reactions. 22 There are few reports for the electrochemical amination of PhOCH 3 in a strong acidic condition with hydroxylamine as an aminating reagent. [23][24][25] In this report, an Nf-MWCNT modied glassy carbon electrode, designated as GCE/ Nf-MWCNT, has been used as a specic electrode system for electrochemical molecular conversion of PhOCH 3 to highly-redox active surface-conned HQ, i.e., HQ immobilized on Nf-MWCNT, i.e., GCE/Nf-MWCNT@HQ, in presence of a dilute H 2 O 2 solution.…”