The production of magnetic shields using high-temperature superconductors (HTS) is not
straightforward, as these materials are brittle ceramics. In this paper, we report
the results of investigations concerning the use of the electrophoretic deposition
(EPD) technique to produce magnetic shields of various shapes and with large
surface areas, in the form of a thick coating of HTS on a metallic substrate. For
the first time, we report shielding characterization of samples prepared by the
EPD technique. The most important problems concern the choice of the process
parameters and the heat treatment of the coating, in order to obtain a dense
and well-connected polycrystalline system. We have used the HTS compound
YBa2Cu3O7−x
as the coating material and silver as the substrate. An optimized heat treatment, in
an atmosphere with poor oxygen content, was chosen following experimental
investigations. Different samples were produced in the form of slabs for
chemical, structural and electrical characterization. A cylindrical sample was
prepared for magnetic shielding measurements at 77 K. With an applied
magnetic field parallel to its axis, the cylinder presents a high level of shielding
(>80 dB)
at low frequencies, for applied inductions lower than 0.1 mT. If the applied induction is
higher than 0.25 mT, the magnetic field inside the cylinder strongly increases. This value is
close to the field of penetration given by Bean’s model, taking a critical current density of
500 A cm−2
measured by the four-probe technique on similar samples.