Abstract:Anaerobic digestion (AD) is a biological decomposition process that occurs in the absence of oxygen. The decomposition of organic matter is a multi-step process of series and parallel reactions that occurs in four stages namely hydrolysis, acidogenesis, acetogenesis and methanogene. Most of the control in anaerobic digestion is undertaken directly by the micro-organisms themselves, however, the operational conditions such as temperature, pH, essential trace nutrients and toxicants can play a major role in modi… Show more
“…When the bioreactor is run at optimal conditions, production of the bioenergy such as methane (60-70%) and stabilised digestate by AD creates economic opportunities and eases pollution [8,11,12]. The AD process utilizes microorganism degradation potential in an ecologically sustainable [13][14][15], odour-reducing, and pathogenic organism-degrading process, especially in reactors running at mesophilic (25-45 • C) and thermophilic (>45 • C) temperatures [14,15]. Furthermore, produced biogas often contains impurities such as H 2 S and CO 2 , which lower the calorific value of biogas and are detrimental to equipment like pipes and combustion engines [3,16].…”
In this study, the principle of sustaining circular economy is presented as a way of recovering valuable resources from wastewater and utilizing its energy potential via anaerobic digestion (AD) of municipality wastewater. Biostimulation of the AD process was investigated to improve its treatability efficiency, biogas production, and kinetic stability. Addressing this together with agricultural waste such as eggshells (CE), banana peel (PB), and calcined banana peels (BI) were employed and compared to magnetite (Fe3O4) as biostimulation additives via 1 L biochemical methane potential tests. With a working volume of 0.8 L (charge with inoculum to substrate ratio of 3:5 v/v) and 1.5 g of the additives, each bioreactor was operated at a mesophilic temperature of 40 °C for 30 days while being compared to a control bioreactor. Scanning electron microscopy and energy dispersive X-ray (SEM/EDX) analysis was used to reveal the absorbent’s morphology at high magnification of 10 kx and surface pore size of 20.8 µm. The results showed over 70% biodegradation efficiency in removing the organic contaminants (chemical oxygen demand, color, and turbidity) as well as enhancing the biogas production. Among the setups, the bioreactor with Fe3O4 additives was found to be the most efficient, with an average daily biogas production of 40 mL/day and a cumulative yield of 1117 mL/day. The kinetic dynamics were evaluated with the cumulative biogas produced by each bioreactor via the first order modified Gompertz and Chen and Hashimoto kinetic models. The modified Gompertz model was found to be the most reliable, with good predictability.
“…When the bioreactor is run at optimal conditions, production of the bioenergy such as methane (60-70%) and stabilised digestate by AD creates economic opportunities and eases pollution [8,11,12]. The AD process utilizes microorganism degradation potential in an ecologically sustainable [13][14][15], odour-reducing, and pathogenic organism-degrading process, especially in reactors running at mesophilic (25-45 • C) and thermophilic (>45 • C) temperatures [14,15]. Furthermore, produced biogas often contains impurities such as H 2 S and CO 2 , which lower the calorific value of biogas and are detrimental to equipment like pipes and combustion engines [3,16].…”
In this study, the principle of sustaining circular economy is presented as a way of recovering valuable resources from wastewater and utilizing its energy potential via anaerobic digestion (AD) of municipality wastewater. Biostimulation of the AD process was investigated to improve its treatability efficiency, biogas production, and kinetic stability. Addressing this together with agricultural waste such as eggshells (CE), banana peel (PB), and calcined banana peels (BI) were employed and compared to magnetite (Fe3O4) as biostimulation additives via 1 L biochemical methane potential tests. With a working volume of 0.8 L (charge with inoculum to substrate ratio of 3:5 v/v) and 1.5 g of the additives, each bioreactor was operated at a mesophilic temperature of 40 °C for 30 days while being compared to a control bioreactor. Scanning electron microscopy and energy dispersive X-ray (SEM/EDX) analysis was used to reveal the absorbent’s morphology at high magnification of 10 kx and surface pore size of 20.8 µm. The results showed over 70% biodegradation efficiency in removing the organic contaminants (chemical oxygen demand, color, and turbidity) as well as enhancing the biogas production. Among the setups, the bioreactor with Fe3O4 additives was found to be the most efficient, with an average daily biogas production of 40 mL/day and a cumulative yield of 1117 mL/day. The kinetic dynamics were evaluated with the cumulative biogas produced by each bioreactor via the first order modified Gompertz and Chen and Hashimoto kinetic models. The modified Gompertz model was found to be the most reliable, with good predictability.
“…It is estimated that a total quantity of 4 × 10 8 t/year of chicken manure is being produced in China, and most of it will be transferred into the natural environment directly, causing serious environmental problems [1]. Using energy conversion technologies such as anaerobic digestion (AD) to deal with various bio-wastes like chicken manure, cow dung, and other various agricultural residues has been an efficient and popular approach for many years because it produces clean energy without polluting the environment [2,3]. However, it is common for ammonia inhibition to have a negative impact on the stability of AD systems [4] and to even cause AD failure when the ammonia concentration increases to a certain range [5,6].…”
Poultry manure is the main source of agricultural and rural non-point source pollution, and its effective disposal through anaerobic digestion (AD) is of great significance; meanwhile, the high nitrogen content of chicken manure makes it a typical feedstock for anaerobic digestion. The performance of chicken-manure-based AD at gradient organic loading rates (OLRs) in a continuous stirred tank reactor (CSTR) was investigated herein. The whole AD process was divided into five stages according to different OLRs, and it lasted for 150 days. The results showed that the biogas yield increased with increasing OLR, which was based on the volatile solids (VS), before reaching up to 11.5 g VS/(L·d), while the methane content was kept relatively stable and maintained at approximately 60%. However, when the VS was further increased to 11.5 g VS/(L·d), the total ammonia nitrogen (TAN), pH, and alkalinity (CaCO3) rose to 2560 mg·L−1, 8.2, and 15,000 mg·L−1, respectively, while the volumetric biogas production rate (VBPR), methane content, and VS removal efficiency decreased to 0.30 L·(L·d)−1, 45%, and 40%, respectively. Therefore, the AD performance immediately deteriorated and ammonia inhibition occurred. Further analysis demonstrated that the microbial biomass yield and concentrations dropped dramatically in this period. These results indicated that the AD stayed steady when the OLR was lower than 11.5 g VS/(L·d); this also provides valuable information for improving the efficiency and stability of AD of a nitrogen-rich substrate.
“…Hence it gives a Carbon/ Nitrogen ratio of 28.63, which is acceptable. For high methane yield a Carbon/Nitrogen ratio between 20:1-30:1 is considered appropriate [17]. A protein content of 11% was also found.…”
Different methods and processes of optimizing the yield of biogas are currently being explored globally. In this study, the use of Iron oxide nanoparticles as an additive to improve the biogas production was carried out. Iron oxide nanoparticles (ION) were synthesized by hydrothermal method. And subsequently, the biomethane potential test was conducted in a 500 mL batch reactor set at mesophilic conditions for a retention time of 15 days. A combination ratio of 100ppm ION to 1.6 g/VS winery solid waste (WSW) was used to run duplicate experiments. Results showed a cumulative biogas yield of 17,17mL /g.VSadded for WSW alone (W1) compared to 56,93mL/g.VSadded for the combination of WSW and ION (W2) which represents a biogas increase of 232%. In conclusion, ION has chemical properties that boost biogas production irrespective of the type of substrate used. The finding is of interest to the biogas industry along with waste management practitioners.
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