Amines are considered
as an emerging class of atmospheric pollutants
that are of great importance to atmospheric chemistry and new particle
formation. As a typical amine, 2-amino-2-methyl-1-propanol (AMP) is
one of the proposed solvents for capturing CO2 from flue
gas streams in amine-based post-combustion CO2 capture
plants, and it is expected to result in AMP emission and secondary
product formation in the atmosphere. However, the current knowledge
of its atmospheric chemistry and kinetics is poorly understood, particularly
in a reactive environment. In this work, we used the CSIRO smog chamber
to study the photo-oxidation of AMP in the presence of volatile organic
compound (VOC)–NOx surrogate mixtures over a range of initial
amine concentrations. O3 formation was significantly inhibited
when AMP was added to the surrogate VOC–NOx mixtures, implying
that AMP could alter known atmospheric chemical reaction pathways
and the prevailing reactivity. Simultaneously, a large amount of AMP-derived
secondary aerosol was formed, with a considerably high aerosol mass
yield (i.e., ratio of aerosol formed to reacted AMP) of 1.06 ±
0.20. Based on updated knowledge of its kinetics, oxidation pathways,
and product yields, we have developed a new mechanism (designated
as CSIAMP-19), integrated it into the Carbon Bond 6 (CB6) chemical
mechanism, and evaluated it against available smog chamber data. Compared
with the existing AMP mechanism (designated as CarterAMP-08), the
modified CB6 with CSIAMP-19 mechanism improves prediction against
AMP–VOC–NOx experiments across a range of initial AMP
concentrations, within ±10% model error for gross ozone production.
Our results contribute to scientific understanding of AMP photochemistry
and to the development of the chemical mechanism of other amines.
Once some potential limitations are considered, the updated AMP reaction
scheme can be further embedded
into the chemical transport model for regional modeling scenarios
where AMP-related emissions are of concern.