“…In the last few years, a great scientific effort has been made to deeply understand the coupling mechanisms among colloidal quantum dots (QDs) interacting with each other when spaced at nanometric and sub-nanometric distances. [1][2][3][4][5][6][7][8][9] The elucidation of the interaction mechanisms among the QDs both in solution and in solid-state can open the opportunity to realize highly efficient charge transfer systems for optoelectronic devices and take a jump towards new fancy applications like quantum computing, [2,3,10] spintronic devices, [11] biosensors, [12,13] solar cells [14,15] and chiralinduced spin selectivity effect. [16] In these applications, the surface chemistry of the QDs, often controlled by the ligands, [17] plays a key role and an adequate understanding of the type of coupling involved that takes also in consideration the role of the organic capping layer is needed.…”