It is commonly assumed that recognition and discrimination of chirality, both in nature and in artificial systems, depend solely on spatial effects. However, recent studies have suggested that charge redistribution in chiral molecules manifests an enantiospecific preference in electron spin orientation. We therefore reasoned that the induced spin polarization may affect enantiorecognition through exchange interactions. Here we show experimentally that the interaction of chiral molecules with a perpendicularly magnetized substrate is enantiospecific. Thus, one enantiomer adsorbs preferentially when the magnetic dipole is pointing up, whereas the other adsorbs faster for the opposite alignment of the magnetization. The interaction is not controlled by the magnetic field per se, but rather by the electron spin orientations, and opens prospects for a distinct approach to enantiomeric separations.
Recent studies have shown a number of surprising vortex dynamics phenomena
both in low and high temperature superconductors, which include: low frequency
noise, slow voltage oscillations, history dependent dynamic response, memory of
the direction, amplitude, duration, and frequency of the previously applied
current, suppression of a large ac vortex response by a very small dc bias, and
a strong frequency dependence. Taken together, these phenomena are incompatible
with the current understanding of bulk vortex dynamics. We propose a generic
mechanism to account for these observations in terms of the competition between
the injection of a disordered vortex phase through the surface barriers at the
sample edges, and the annealing of this metastable disorder by the transport
current. The model is confirmed by investigating the current distribution
across NbSe2 single crystals using arrays of Hall sensors. For an ac current
only narrow regions near the edges are in the pinned disordered phase resulting
in a large response. In the presence of a dc bias a wide region of the sample
is filled by the disordered phase preventing vortex motion. The resulting
spatial variation of the disorder across the sample acts as an active memory of
the previously applied current sequence.Comment: 15 pages 4 figures. Accepted for publication in Natur
Ferromagnets are commonly magnetized by either external magnetic fields or spin polarized currents. The manipulation of magnetization by spin-current occurs through the spin-transfer-torque effect, which is applied, for example, in modern magnetoresistive random access memory. However, the current density required for the spin-transfer torque is of the order of 1 × 106 A·cm−2, or about 1 × 1025 electrons s−1 cm−2. This relatively high current density significantly affects the devices' structure and performance. Here we demonstrate magnetization switching of ferromagnetic thin layers that is induced solely by adsorption of chiral molecules. In this case, about 1013 electrons per cm2 are sufficient to induce magnetization reversal. The direction of the magnetization depends on the handedness of the adsorbed chiral molecules. Local magnetization switching is achieved by adsorbing a chiral self-assembled molecular monolayer on a gold-coated ferromagnetic layer with perpendicular magnetic anisotropy. These results present a simple low-power magnetization mechanism when operating at ambient conditions.
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