This study reports
the impact of a biodiesel, produced from inedible
neem oil through a transesterification process, on the formation and
physicochemical properties of soot from diesel/biodiesel blends. A
smoke point test for the diesel/biodiesel blends is presented that
reveals a nonlinear reduction in the sooting propensity of diesel
with increasing proportion of neem-biodiesel in the blends. Soot particles
from the diffusion flames of pure diesel and a diesel/biodiesel blend
are analyzed through thermogravimetric analysis, high-resolution transmission
electron microscopy, electron energy loss spectroscopy, Fourier transform
infrared spectroscopy, X-ray diffraction, and energy-dispersive X-ray
spectroscopy techniques. Soot from the blended fuel was found to be
more reactive in air than that from pure diesel. To understand and
explain the reactivity differences, the nanostructural changes (the
sizes of aromatics and the primary particles comprising soot, and
the thickness of the nanocrystallites) along with the variation in
the chemical composition (the concentration of oxygenated functional
groups, σ and π bonding, and the aliphatic and aromatic
content) in soot arising from the addition of biodiesel to diesel
are determined. The presence of neem-biodiesel in the fuel was found
to enhance the concentrations of aliphatic and oxygenated groups on
soot, possibly due to the high amounts of saturated fatty acid methyl
esters and the presence of fuel-bound oxygen in it.