An examination of the decrease of surface-activity method of measuring self-diffusion coefficients in wustite and cobaltous oxide

Carter, R. E.; Richardson, F. D.

doi:10.1007/bf03398364

Cited by 18 publications

(26 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The and acts as a coating against hydration. [4][5][6][7][8][9][10][11][12][13][14][15][16] Some In case of In 1988, Bergman and Song [8] studied the Ca-Fe-O system slowly cooled slag, the FeO seems to be homogeneously and concluded that the system is not eutectic, supporting distributed in the free-CaO phase, and the hydration of the the phase diagram suggested by Abbatista et al [5] On this free CaO becomes easier.…”

Section: Introductionmentioning

confidence: 99%

Solid-state reaction kinetics of the system CaO-FeO

Fukuyama

Hossain

Nagata

2002

Metall Mater Trans B

View full text Add to dashboard Cite

The solid-state reaction mechanisms of the CaO-FeO system have been studied by a diffusion couple method in the temperature range of 1073 to 1273 K, under controlled oxygen-partial pressures. The interdiffusivities and intrinsic diffusivities of Ca 2+ and Fe 2+ have been determined in the limited FeO solid-solution range. Based on the obtained results, a solid-state reaction model of the system has been developed, taking account of the formation of the Ca 2 Fe 2 O 5 phase. According to the model, the diffusivities of Fe 3+ in the Ca 2 Fe 2 O 5 phase have been estimated at 1273 K.

show abstract

Section: Introductionmentioning

confidence: 99%

Solid-state reaction kinetics of the system CaO-FeO

Fukuyama

Hossain

Nagata

2002

Metall Mater Trans B

View full text Add to dashboard Cite

show abstract

“…The predictions of Wagner's theory for n-type and p-type oxides have been extensively examined by several workers [120][121][122][123][124][125][126][127][128][129]. For many systems, the obtained rate constants are generally several orders of magnitude larger than those which one would calculate from lattice diffusion data from Eq.…”

Section: E2 Diffusion-controlled Oxidationmentioning

confidence: 84%

High‐Temperature Oxidation

Sequeira

2011

Uhlig's Corrosion Handbook

View full text Add to dashboard Cite

“…13,[19][20][21][22][23][26][27][28][29] Figure 8 shows the effective diffusion coefficients obtained in this study as a function of oxygen partial pressure with several typical reported values. 21,23,26,29) The self diffusion coefficient of cobalt reported by Mrowec and Przybylski 23) with the sample obtained from high temperature oxidation experiments of cobalt at 1373 K is in good agreement to that obtained in this study.…”

Section: The Effective Diffusion Coefficients Of Cobalt and Oxygen Inmentioning

confidence: 99%

Quantitative Prediction of Voids Formation in a Growing Cobaltous Oxide Scale at 1373 K

et al. 2007

View full text Add to dashboard Cite

Quantitative prediction of voids formation is demonstrated for CoO scale formed at 1373 K. Calculations of ion fluxes and their divergence in CoO scales can predict the void formation in the scale which mostly occurs in the vicinity of the metal/oxide interface. The volume fraction of voids is found to be maximum at the initial surface. These predictions are in good agreement with the observed morphology of CoO scale obtained in high temperature oxidation of cobalt at 1373 K.

show abstract

An examination of the decrease of surface-activity method of measuring self-diffusion coefficients in wustite and cobaltous oxide

Cited by 18 publications

References 10 publications

Solid-state reaction kinetics of the system CaO-FeO

Solid-state reaction kinetics of the system CaO-FeO

High‐Temperature Oxidation

Quantitative Prediction of Voids Formation in a Growing Cobaltous Oxide Scale at 1373 K

Contact Info

Product

Resources

About