The present article is a review of the field of X-ray excited electron spectroscopy for the period 1972-73; it is the second review of this topic in the Analytical Chemistry Fundamental Reviews. The first review (1) covered the literature abstracted beginning with volume 69 of Chemical Abstracts through the December 16, 1971, issue. The present review covers all literature abstracted in Chemical Abstracts starting with the December 23, 1971, issue through the December 10, 1973, issue. The present article also contains a sampling of the literature on applications of Auger Spectroscopy. For the sake of brevity the term ESCA will be used to refer to X-ray excited photoelectron spectroscopy and AES for Auger electron spectroscopy in the present review.