1995
DOI: 10.1016/0010-938x(95)00104-r
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An electrochemical impedance study on atmospheric corrosion of steels in a cyclic wet-dry condition

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Cited by 136 publications
(69 citation statements)
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“…It is, however, of critical importance that such measures are sustain- 46 able in terms of not compromising the historic and cultural heritage of these vehicles by excessive 47 repair, replacements, and other maintenance techniques such as coatings. The sustainable conser- 48 vation of these artefacts would include full understanding of the critical parameters that are respon- 49 sible for initiating and accelerated propagation of corrosion. Linking these critical attributes to 50 controlled environment facilities to optimise their design for achieving these goals economically is 51 the objective of the present research.…”
Section: Proof Copy [Mpc20120016]mentioning
confidence: 99%
See 1 more Smart Citation
“…It is, however, of critical importance that such measures are sustain- 46 able in terms of not compromising the historic and cultural heritage of these vehicles by excessive 47 repair, replacements, and other maintenance techniques such as coatings. The sustainable conser- 48 vation of these artefacts would include full understanding of the critical parameters that are respon- 49 sible for initiating and accelerated propagation of corrosion. Linking these critical attributes to 50 controlled environment facilities to optimise their design for achieving these goals economically is 51 the objective of the present research.…”
Section: Proof Copy [Mpc20120016]mentioning
confidence: 99%
“…The addition of chlorides and sulphurs, in the form of sulphates, sulphides, sulphites, and sul-284 phurous salts, in the atmospheric environment, increases the corrosion rate [49][50][51][52]. Salts play 285 three main roles in accelerating corrosion: (a) they are imperfections on the surfaces and thereby 286 points of corrosion nucleation, (b) they form a hygroscopic salt film on the substrate surface that 287 keeps the surface wet for longer periods of time because the salt layer causes the surface to remain 288 wet at a lower relative humidity compared to clean surfaces, and (c) salts act to increase the con-289 ductivity of the thin electrolyte film that drives the electrochemical reaction, i.e., corrosion [52,53].…”
mentioning
confidence: 99%
“…Electrochemical impedance spectroscopy (EIS) has proven to be an effective technique for monitoring the corrosivity of haze and related mechanisms of steel. Nishikata et al [29][30][31][32][33][34][35][36] used EIS to study the corrosivity of atmosphere to different types of steels, and the effects of electrolyte concentration and pH value on the atmospheric corrosivity of metal were also studied. EIS was used to study the atmospheric corrosion of steel under an electrolyte film in wet-dry cycles by Dong et al 37 Leygraf et al [38][39][40] used situ X-ray transmission spectromicroscopy, infrared reflection absorption spectroscopy (IRAS) and a quartz crystal microbalance to investigate the atmospheric corrosivity of metals.…”
Section: Introductionmentioning
confidence: 99%
“…The presence of painting or inorganic coating and thin layer of electrolyte could be resulted in extremely high resistance. In addition, the error was also occurred from ohmic drop between the reference and working electrodes and uneven current distribution over the working electrode [5][6][7][8]. These errors could be compensated by using alternating current (AC) impedance techniques or electrochemical impedance spectroscopy (EIS) method [9].…”
Section: Introductionmentioning
confidence: 99%