Expressions are derived for the electric field, potential, depletion width, and capacitance for a heterojunction with a built‐in homojunction due to interdiffusion including the effects of interface states at the metallurgical junction. It is found that when the total interface charge is equal to the total excess charge stored in the interdiffused region, a maximum for the apparent built‐in potential is obtained. This is always greater than the built‐in potential of the system and increases in a square law fashion with the length of the interdiffused region.