2005
DOI: 10.1016/j.aca.2005.02.057
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Amperometric sensor for glucose based on electrochemically polymerized tetraruthenated nickel-porphyrin

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Cited by 62 publications
(52 citation statements)
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“…Such a 20-30 mV shift has been assigned to a strong interaction of glucose with Ni II (OH) 2 [26,27]. However, generally, the heterogeneous electron transfer rate should increase and the overpotential should decrease as the interaction between the catalyst and the substrate is increased.…”
Section: Glucose Determinationmentioning
confidence: 96%
“…Such a 20-30 mV shift has been assigned to a strong interaction of glucose with Ni II (OH) 2 [26,27]. However, generally, the heterogeneous electron transfer rate should increase and the overpotential should decrease as the interaction between the catalyst and the substrate is increased.…”
Section: Glucose Determinationmentioning
confidence: 96%
“…In particular, the use of porphyrins containing ruthenium complexes in the peripheral positions, as the starting material for electropolymerization by cyclic voltammetry, has excelled over other methods [35][36][37].…”
Section: Introductionmentioning
confidence: 99%
“…The PA-PADPP covered electrode was rinsed with chloroform to remove the excess monomer before 10 mL of the ODNprobe (1.35 nmol) was pipetted over the electrodes surface. After measurement by cyclic voltammetry in LiClO 4 with ACN as solvent, the electrode was kept at room temperature for 1 hour. The resulting ODN-probed PA-PADPP/ITO bioelectrode was thoroughly washed with a phosphate buffer solution (PBS) of pH 7.4 to rinse off any loosely bound ODN-probe from the electrode.…”
Section: Preparation Of the Dna Sensormentioning
confidence: 99%
“…Among these materials, metalloporphyrins have been used as attractive agents for electrode modification and are useful in photoelectrochemical processes due to their strong light absorption in the visible to near-ultraviolet region [2,3]. Moreover, modifying electrode surfaces with electropolymerized porphyrin films have been studied because of the ease of film formation and their potential in catalysis and sensor applications [4,5]. An attractive future direction in porphyrin research would be to apply their characteristics for the production of electricity or fuels [1].…”
Section: Introductionmentioning
confidence: 99%