Amidation of aldehydes using mono-cationic half-sandwich rhodium(III) complexes with functionalized phenylhydrazone ligands

Devika, Neelakandan; Ananthalakshmi, S.; Raja, Nandhagopal; Gupta, Gajendra; Therrien, Bruno

doi:10.1016/j.jorganchem.2019.02.018

Cited by 9 publications

(1 citation statement)

References 76 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In this regard, it is especially interesting to examine the interaction of metal‐based supramolecular entities and DNA. This specific biological application of SCCs has been promoted by Hannon, Therrien, Sleiman, Mao, Chi, and others . The motivation to study extent of interaction between SCCs and DNA probably stems from the knowledge that cisplatin and other Pt(II) based inorganic complexes coordinate with purine bases in DNA leading to death of cancer cells .…”

Section: Introductionmentioning

confidence: 99%

A Pt(II)‐based Hexagonal Ionic Supramolecular Coordination Complex and its DNA Interactions.

et al. 2019

View full text Add to dashboard Cite

A pyrimidine based organic donor clip with pendant pyridyl rings has been designed for its use in construction of a supramolecular coordination complex (SCC). This molecule is a new addition to the library of "nitrogen donor ligands" that have been used as building blocks to yield SCCs of various shapes and sizes. Its self-assembly with a suitable complementary metal based acceptor tecton yielded a unique [1 + 1] hexagonal macrocycle that was characterized using a suite of analytical tools. The platina metallacycle has a hexagonal cavity and is nano-dimensional in size. The self-assembled ensembles were found to interact significantly with DNA and they also demonstrate positive nuclease activity with DNA relative to its donor/acceptor building blocks.

show abstract

Section: Introductionmentioning

confidence: 99%

A Pt(II)‐based Hexagonal Ionic Supramolecular Coordination Complex and its DNA Interactions.

et al. 2019

View full text Add to dashboard Cite

show abstract

Organometallic ruthenium complexes derived from anthracene and pyrene chromophores: Synthesis and photophysical properties

Gupta,

Choe,

Kim

et al. 2024

Bulletin Korean Chem Soc

Self Cite

View full text Add to dashboard Cite

Two new monopyridyl‐based Anthracene and Pyrene ligands were synthesized and employed to design Ruthenium‐coordinated organometallic complexes, RuAnthra and RuPyrene, respectively. The ligands and their metal complexes were fully characterized by different analytical techniques, including multinuclear 1D‐ and 2D‐NMR, electrospray ionization‐mass spectrometry, UV–Vis, fluorescence spectroscopy, and elemental analysis. Furthermore, their photophysical properties were studied in different solvents with increasing polarity using UV–Vis and fluorescence spectroscopy, showing less or no significant solvolysis effect. The average emission lifetimes of the complexes were further determined using time‐resolved emission spectroscopy. Additionally, the ligands and their metal complexes showed excellent ability to generate singlet oxygen and can be useful for several important potential applications.

show abstract

Appraisal of Ruthenium(II) complexes of (4-phenoxyphenylazo) ligands for the synthesis of primary amides by dint of hydroxylamine hydrochloride and aldehydes

Vinoth

Indira

Sounthararajan

et al. 2019

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Amidation of aldehydes using mono-cationic half-sandwich rhodium(III) complexes with functionalized phenylhydrazone ligands

Cited by 9 publications

References 76 publications

A Pt(II)‐based Hexagonal Ionic Supramolecular Coordination Complex and its DNA Interactions.

A Pt(II)‐based Hexagonal Ionic Supramolecular Coordination Complex and its DNA Interactions.

Organometallic ruthenium complexes derived from anthracene and pyrene chromophores: Synthesis and photophysical properties

Appraisal of Ruthenium(II) complexes of (4-phenoxyphenylazo) ligands for the synthesis of primary amides by dint of hydroxylamine hydrochloride and aldehydes

Contact Info

Product

Resources

About